Teoretičeskaâ i matematičeskaâ fizika, Tome 8 (1971) no. 3, pp. 392-400
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I. V. Aleksandrov. Quantum-statistical derivation of the equations of chemical kinetics for reactions of the type $AX+B=A+BX$. Teoretičeskaâ i matematičeskaâ fizika, Tome 8 (1971) no. 3, pp. 392-400. http://geodesic.mathdoc.fr/item/TMF_1971_8_3_a10/
@article{TMF_1971_8_3_a10,
author = {I. V. Aleksandrov},
title = {Quantum-statistical derivation of the equations of chemical kinetics for reactions of the type $AX+B=A+BX$},
journal = {Teoreti\v{c}eska\^a i matemati\v{c}eska\^a fizika},
pages = {392--400},
year = {1971},
volume = {8},
number = {3},
language = {ru},
url = {http://geodesic.mathdoc.fr/item/TMF_1971_8_3_a10/}
}
TY - JOUR
AU - I. V. Aleksandrov
TI - Quantum-statistical derivation of the equations of chemical kinetics for reactions of the type $AX+B=A+BX$
JO - Teoretičeskaâ i matematičeskaâ fizika
PY - 1971
SP - 392
EP - 400
VL - 8
IS - 3
UR - http://geodesic.mathdoc.fr/item/TMF_1971_8_3_a10/
LA - ru
ID - TMF_1971_8_3_a10
ER -
%0 Journal Article
%A I. V. Aleksandrov
%T Quantum-statistical derivation of the equations of chemical kinetics for reactions of the type $AX+B=A+BX$
%J Teoretičeskaâ i matematičeskaâ fizika
%D 1971
%P 392-400
%V 8
%N 3
%U http://geodesic.mathdoc.fr/item/TMF_1971_8_3_a10/
%G ru
%F TMF_1971_8_3_a10
The method of an earlier paper [1] is used in a quantum-statistical derivation of the equations of chemical kinetics; sufficient conditions for the applicability of these equations are formulated and general quantum-mechanical formulas are obtained for the rate constants of a bimolecular reaction. The formulas are obtained in a universal form suitable for realization in both a gaseous and liquid phase.
