Spectrum of molecular electron energy operators in spaces of functions of specified symmetry
Teoretičeskaâ i matematičeskaâ fizika, Tome 1 (1969) no. 2, pp. 295-302
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The spectrum of the molecular electron energy operator $H$ is investigated for the case of molecules with fixed nuclei situated such that transformations of the point group $G$ carry identical nuclei into each other. On the spaces of electron wavefuuctions corresponding to the product of irreducible representations of the permutation groups $S_n$ and $G$, the limiting spectrum $H$ is found, and the existence of an infinite number of points of the discrete spectrum is proved for neutral molecules and for positive molecular ions.
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