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Brown representability approximates the homotopy category of spectra by means of cohomology functors defined on finite spectra. We will show that if a model category $\cal K$ is suitably determined by $\lambda$-small objects then its homotopy category $Ho(\cal K)$ is approximated by cohomology functors defined on those $\lambda$-small objects. In the case of simplicial sets, we have $\lambda = \omega_1$, i.e., $\lambda$-small means countable.
@article{TAC_2005_14_a18, author = {Jiri Rosicky}, title = {Generalized {Brown} representability in homotopy categories}, journal = {Theory and applications of categories}, pages = {451--479}, publisher = {mathdoc}, volume = {14}, year = {2005}, language = {en}, url = {http://geodesic.mathdoc.fr/item/TAC_2005_14_a18/} }
Jiri Rosicky. Generalized Brown representability in homotopy categories. Theory and applications of categories, Tome 14 (2005), pp. 451-479. http://geodesic.mathdoc.fr/item/TAC_2005_14_a18/