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To a bicategory B (in the sense of Bénabou) we assign a simplicial set Ner(B), the (geometric) nerve of B, which completely encodes the structure of B as a bicategory. As a simplicial set Ner(B) is a subcomplex of its 2-Coskeleton and itself isomorphic to its 3-Coskeleton, what we call a 2-dimensional Postnikov complex. We then give, somewhat more delicately, a complete characterization of those simplicial sets which are the nerves of bicategories as certain 2-dimensional Postnikov complexes which satisfy certain restricted `exact horn-lifting' conditions whose satisfaction is controlled by (and here defines) subsets of (abstractly) invertible 2 and 1-simplices. Those complexes which have, at minimum, their degenerate 2-simplices always invertible and have an invertible 2-simplex $\chi_2^1(x_{12}, x_{01})$ present for each `composable pair' $(x_{12}, \_ , x_{01}) \in \mhorn_2^1$ are exactly the nerves of bicategories. At the other extreme, where all 2 and 1-simplices are invertible, are those Kan complexes in which the Kan conditions are satisfied exactly in all dimensions >2. These are exactly the nerves of bigroupoids - all 2-cells are isomorphisms and all 1-cells are equivalences.
@article{TAC_2001_9_a9, author = {John W. Duskin}, title = {Simplicial matrices and the nerves of weak n-categories {I: nerves} of bicategories}, journal = {Theory and applications of categories}, pages = {198--308}, publisher = {mathdoc}, volume = {9}, year = {2001}, language = {en}, url = {http://geodesic.mathdoc.fr/item/TAC_2001_9_a9/} }
John W. Duskin. Simplicial matrices and the nerves of weak n-categories I: nerves of bicategories. Theory and applications of categories, CT2000, Tome 9 (2001), pp. 198-308. http://geodesic.mathdoc.fr/item/TAC_2001_9_a9/