Geodesic
Kinetics of electrochemical formation silver-tungsten coatings from the ammonium sulfate electrolyte
Problemy fiziki, matematiki i tehniki, no. 1 (2023), pp. 7-12.

Voir la notice de l'article provenant de la source Math-Net.Ru

The mechanism of electrochemical deposition of silver-tungsten thin films from the ammonium sulfate solution has been studied. The dependencies of the coating formation parameters (exchange current, transfer coefficient and nucleation parameters) on a sodium tungstate concentration in the electrolyte and deposition conditions have been defined. It was shown that the introduction of tungsten reduces the crystallization overvoltage and critical nucleus radius as well as reduces the average crystal grain size in the coating with the increase in the rate of nucleation. Coating structure has been researched, the elemental analysis has been done and grain size distribution density in a silver-tungsten coating has been calculated using energy dispersive X-ray spectroscopy.
Keywords: silver, tungsten, composite electrochemical coatings, nucleation, crystallization. 
@article{PFMT_2023_1_a0,
     author = {N. V. Bogush and I. I. Kuzmar and L. K. Kushner and A. A. Khmyl},
     title = {Kinetics of electrochemical formation silver-tungsten coatings from the ammonium sulfate electrolyte},
     journal = {Problemy fiziki, matematiki i tehniki},
     pages = {7--12},
     publisher = {mathdoc},
     number = {1},
     year = {2023},
     language = {ru},
     url = {http://geodesic.mathdoc.fr/item/PFMT_2023_1_a0/}
}
TY  - JOUR
AU  - N. V. Bogush
AU  - I. I. Kuzmar
AU  - L. K. Kushner
AU  - A. A. Khmyl
TI  - Kinetics of electrochemical formation silver-tungsten coatings from the ammonium sulfate electrolyte
JO  - Problemy fiziki, matematiki i tehniki
PY  - 2023
SP  - 7
EP  - 12
IS  - 1
PB  - mathdoc
UR  - http://geodesic.mathdoc.fr/item/PFMT_2023_1_a0/
LA  - ru
ID  - PFMT_2023_1_a0
ER  - 
%0 Journal Article
%A N. V. Bogush
%A I. I. Kuzmar
%A L. K. Kushner
%A A. A. Khmyl
%T Kinetics of electrochemical formation silver-tungsten coatings from the ammonium sulfate electrolyte
%J Problemy fiziki, matematiki i tehniki
%D 2023
%P 7-12
%N 1
%I mathdoc
%U http://geodesic.mathdoc.fr/item/PFMT_2023_1_a0/
%G ru
%F PFMT_2023_1_a0
N. V. Bogush; I. I. Kuzmar; L. K. Kushner; A. A. Khmyl. Kinetics of electrochemical formation silver-tungsten coatings from the ammonium sulfate electrolyte. Problemy fiziki, matematiki i tehniki, no. 1 (2023), pp. 7-12. http://geodesic.mathdoc.fr/item/PFMT_2023_1_a0/

[1] R.Dzh. Ratish i dr., “Korrozionnye problemy elektronnogo oborudovaniya. Obzor”, Korroziya: Materialy, zaschita, 2021, no. 4, 33–43

[2] I.G. Zhikhareva i dr., “Razrabotka antikorrozionnykh pokrytii, ekspluatiruemykh v usloviyakh arktiki”, Vestnik tekhnologicheskogo universiteta, 25:9 (2022), 31–35

[3] D.A. Schedrova, V.T. Borisovich, Yu.A. Leonidova, “Formirovanie sprosa na serebro na rynke dragotsennykh metallov”, Ekonomika i upravlenie innovatsiyami, 2018, no. 2, 37–44

[4] S.Ya. Grilikhes, K.I. Tikhonov, Elektroliticheskie i khimicheskie pokrytiya. Teoriya i praktika, Khimiya, L., 1990, 288 pp.

[5] N.V. Bogush, A.A. Khmyl, L.K. Kushner, “Struktura i fiziko-mekhanicheskie svoistva kompozitsionnykh pokrytii serebro-volfram, poluchennykh elektrokhimicheskim metodom”, Doklady BGUIR, 2017, no. 5 (107), 54–61

[6] A.N. Frumkin, Izbrannye trudy: Elektrodnye protsessy, Nauka, M., 1987, 336 pp.

[7] V.K. Vasilets i dr., “Vliyanie ultrazvukovykh kolebanii na kinetiku protsessa elektroosazhdeniya i strukturu pokrytii splavom olovo-vismut”, Doklady BGUIR, 2015, no. 5, 12–18

[8] L.I. Antropov, Teoreticheskaya elektrokhimiya, 4-e izd., Vyssh. shk., M., 1984, 519 pp.

[9] V.M. Rudoi i dr., “O primenenii metoda galvanostaticheskogo vklyucheniya pri issledovanii elektrokristallizatsii na chuzherodnoi podlozhke”, Elektrokhimiya, 11:4 (1975), 566–570

[10] E.A. Rogachev, Fizicheskie osnovy sovremennykh metodov issledovaniya materialov, ucheb. posobie, Minobrnauki Rossii, Omskii gosudarstvennyi tekhnicheskii universitet, Izd-vo OmGTU, Omsk, 2021, 88 pp.

[11] O.A. Slesarenko, Prikladnaya elektrokhimiya: metodicheskie ukazaniya k laboratornym rabotam i kontrolnye zadaniya dlya studentov spetsialnosti 1–47 02 01 «Tekhnologiya poligraficheskikh proizvodstv» zaochnoi formy obucheniya, BGTU, Minsk, 2014, 78 pp.

[12] M.S. Zakharov, V.I. Bakanov, V.V. Pnev, Khronopotentsiometriya, Khimiya, M., 1978, 200 pp.

[13] K. Fetter, Elektrokhimicheskaya kinetika, Khimiya, M., 1967, 856 pp.