Hydrophobization of up-conversion luminescent films based on nanocellulose/MF$_2$:HO particles (M = Sr, Ca) by acrylic resin
Nanosistemy: fizika, himiâ, matematika, Tome 10 (2019) no. 5, pp. 585-598.

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Luminescent hydrophobic composite films based on nanocrystalline (CNC) and nanofibrillated (CNF) cellulose matrix with up-conversion MF$_2$:Ho (M = Ca, Sr) particles and acrylic resin (ACR) as a coating have been synthesized. Flexible, translucent composite films were obtained by molding from the CNC/CNF suspensions with up-conversion particles. ACR coating was applied to the composite film by spraying. Studies have shown that ACR coating with a layer thickness of 7–10 $\mu$m provides hydrophobic properties for the films, increasing the water contact angle up to 100$\pm$2$^\circ$ with a simultaneous improvement in the luminescent properties. Transparency of CNC/CNF/MF$_2$:Ho-ACR films in the visible and near IR region improves by 20–25% without compromising the flexibility and thermal stability. The manufactured water-resistant composite films can be utilized as potential photonics materials, in particular for visualization of near-IR laser radiation and luminescent labels.
Keywords: cellulose nanocrystals, hydrophobicity, acrylic resins, SrF$_2$:HO, CaF$_2$:HO
Mots-clés : cellulose nanofibrils, nanocomposites, up-conversion luminescence films.
@article{NANO_2019_10_5_a10,
     author = {A. A. Luginina and S. V. Kuznetsov and V. V. Voronov and A. D. Yapryntsev and V. K. Ivanov and D. I. Petukhov and A. A. Lyapin and A. S. Ermakov and D. V. Pominova and E. V. Chernova and A. A. Pynenkov and K. N. Nishchev and P. P. Fedorov},
     title = {Hydrophobization of up-conversion luminescent films based on {nanocellulose/MF}$_2${:HO} particles {(M} = {Sr,} {Ca)} by acrylic resin},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {585--598},
     publisher = {mathdoc},
     volume = {10},
     number = {5},
     year = {2019},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2019_10_5_a10/}
}
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AU  - E. V. Chernova
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%A V. V. Voronov
%A A. D. Yapryntsev
%A V. K. Ivanov
%A D. I. Petukhov
%A A. A. Lyapin
%A A. S. Ermakov
%A D. V. Pominova
%A E. V. Chernova
%A A. A. Pynenkov
%A K. N. Nishchev
%A P. P. Fedorov
%T Hydrophobization of up-conversion luminescent films based on nanocellulose/MF$_2$:HO particles (M = Sr, Ca) by acrylic resin
%J Nanosistemy: fizika, himiâ, matematika
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A. A. Luginina; S. V. Kuznetsov; V. V. Voronov; A. D. Yapryntsev; V. K. Ivanov; D. I. Petukhov; A. A. Lyapin; A. S. Ermakov; D. V. Pominova; E. V. Chernova; A. A. Pynenkov; K. N. Nishchev; P. P. Fedorov. Hydrophobization of up-conversion luminescent films based on nanocellulose/MF$_2$:HO particles (M = Sr, Ca) by acrylic resin. Nanosistemy: fizika, himiâ, matematika, Tome 10 (2019) no. 5, pp. 585-598. http://geodesic.mathdoc.fr/item/NANO_2019_10_5_a10/