Transition to the Condensate State for Classical Gases and Clusterization

V. P. Maslov

Matematičeskie zametki, Tome 84 (2008) no. 6, pp. 851-873

Résumé

In this paper, using of the rigorous statement and rigorous proof the Maxwell distribution as an example, we establish estimates of the distribution depending on the parameter $N$, the number of particles. Further, we consider the problem of the occurrence of dimers in a classical gas as an analog of Bose condensation and establish estimates of the lower level of the analog of Bose condensation. We find the relationship of this level to “capture” theory in the scattering problem corresponding to an interaction of the form of the Lennard-Jones potential. This also solves the problem of the Gibbs paradox. We derive the equation of state for a nonideal gas as a result of pair interactions of particles in Lennard-Jones models and, for classical gases, discuss the $\lambda$-transition to the condensed state (the state in which $V_{\text{spec}}$ does not vary with increasing pressure; for heat capacity, this is the $\lambda$-point). We also present new quantum equations of the flow of a neutral gas consisting of particles with an odd number of neutrons in the capillaries in the Sutherland model.

Détail

Mots-clés : Bose condensation, dimer
Keywords: clusterization, scattering theory, Lennard-Jones potential, Maxwell distribution, neutral gas flow.