Influence of the sizes of gas molecules on their diffusion in cross-linked polyethylene
News of the Kabardin-Balkar scientific center of RAS, no. 2 (2005), pp. 55-57.

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This work shows that the decrease in the diffusion coefficient during cross-linking of polymers is due to the “drift” of diffusant gas molecules into cross-links. An increase in the diameter of the gas molecule leads to a change in the “effective” structural characteristics of the cross-linked polymer (C$_{\text{npr}}$ and Z), which further enhances this effect.
Keywords: gas molecule, polyethylene
Mots-clés : diffusion coefficient
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R. M. Khalikov; G. B. Shustov; G. V. Kozlov. Influence of the sizes of gas molecules on their diffusion in cross-linked polyethylene. News of the Kabardin-Balkar scientific center of RAS, no. 2 (2005), pp. 55-57. http://geodesic.mathdoc.fr/item/IZKAB_2005_2_a7/

[1] S. A. Reitlinger, Pronitsaemost polimernykh materialov, Khimiya, M., 1974, 272 pp.

[2] P. Argyrakis, R. Korpelman, “Random walks and reactions on dendrimer strucrutes”, Chem. Phys, 261:2 (2000), 391–398 | DOI

[3] N. I. Nikolaev, Diffuziya v membranakh, Khimiya, M., 1980, 232 pp.

[4] V. V. Teplyakov, S. G. Durgaryan, “Korrelyatsionnyi analiz parametrov gazopronitsatelnosti polimerov”, Vysokomolekulyarnye soedineniya A, 24:7 (1984), 1498–1505

[5] V. V. Teplyakov, S. G. Durgaryan, “O sotnoshenii parametrov pronitsaemosti postoyannykh gazov i uglevodorodov v polimerakh”, Vysokomolekulyarnye soedineniya A, 28:3 (1986), 564–572

[6] G. V. Kozlov, G. E. Zaikov, “Diffusion of gases in semicrystalline polyethylene and its melt”, J. Balkan Tribolog. Association, 10:1 (2004), 41–46

[7] G. V. Kozlov, G. E. Zaikov, “The dependence of diffusive characteristics from the size of penetrant molecules and structure for polyethylenes”, Fractial analysis of polimers: from synthesis to composites, eds. Eds. Koslov G., G. Zaikov, V. Novikov, Nova Scienxe Publishers, New York, 2003, 107–112

[8] J. K. McCauley, “Multifractal description of the statistical equilibrium of chaotic dynamical systems”, Intern. moderm phys. B, 3:6 (1989), 821–852 | DOI | MR

[9] S. Alexander, R. Orbach, “Density of states on fractals: “fractions””, J. Phys. Lett., 43:17 (1982), L625–L631 | DOI