The energy of heavy atoms according to Brown and Ravenhall: the Scott correction
Documenta mathematica, Tome 14 (2009), pp. 463-516.

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Summary: We consider relativistic many-particle operators which -- according to Brown and Ravenhall -- describe the electronic states of heavy atoms. Their ground state energy is investigated in the limit of large nuclear charge and velocity of light. We show that the leading quasi-classical behavior given by the Thomas-Fermi theory is raised by a subleading correction, the Scott correction. Our result is valid for the maximal range of coupling constants, including the critical one. As a technical tool, a Sobolev-Ga­gliar­do-Nirenberg-type inequality is established for the critical atomic Brown-Ravenhall operator. Moreover, we prove sharp upper and lower bounds on the eigenvalues of the hydrogenic Brown-Ravenhall operator up to and including the critical coupling constant.
Classification : 81V45, 81V55, 35Q40, 46N50, 47N50
Keywords: heavy atoms, ground state energy, relativistic Coulomb system, Scott correction, Brown-Ravenhall operator
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     author = {Frank, Rupert L. and Siedentop, Heinz and Warzel, Simone},
     title = {The energy of heavy atoms according to {Brown} and {Ravenhall:} the {Scott} correction},
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Frank, Rupert L.; Siedentop, Heinz; Warzel, Simone. The energy of heavy atoms according to Brown and Ravenhall: the Scott correction. Documenta mathematica, Tome 14 (2009), pp. 463-516. http://geodesic.mathdoc.fr/item/DOCMA_2009__14__a11/