Geodesic
Study of hydrogen-helium permeability of silicate microspheres and sorbent based of them
Čelâbinskij fiziko-matematičeskij žurnal, Tome 9 (2024) no. 2, pp. 247-254.

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The work is devoted to research on the applicability of the membrane-sorption method for the separation of hydrogen-helium mixtures. The sorption dependences of hydrogen and helium absorption were experimentally obtained for synthetic hollow microspheres made of sodium borosilicate glass of the MS-V-1L type, silica microspheres and granular sorbent based on MS-V-1L microspheres. A significant difference in the rates of sorption processes of hydrogen and helium for the sorbents under study was shown. Based on the gas diffusion model, the kinetic characteristics of absorption, permeability and selectivity coefficients, and dynamic characteristics of the processes of sorption of hydrogen and helium of helium-hydrogen mixtures of various compositions by these sorbents were determined. For silica microspheres, the selectivity coefficient with respect to hydrogen and helium at $T = 24\,^\circ$C exceeds $130$, and for a granular sorbent based on MS-V-1L microspheres it is about $1000$ at $T = $110$\,^\circ$C. The high selectivity values of the studied sorbents confirm the possibility and efficiency of using the membrane-sorption method for the separation of hydrogen-helium mixtures.
Keywords: membrane-sorption method, microspheres, helium, hydrogen, selectivity, gas permeability coefficient, gas separation. 
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I. V. Kazanin; V. N. Zinoviev; A. S. Vereshchagin; V. M. Fomin. Study  of hydrogen-helium permeability of silicate microspheres and sorbent based of them. Čelâbinskij fiziko-matematičeskij žurnal, Tome 9 (2024) no. 2, pp. 247-254. http://geodesic.mathdoc.fr/item/CHFMJ_2024_9_2_a9/

[1] Akulov L.A., Devices for separation of gas mixtures, Mashinostroyeniye Publ., Leningrad, 1983 (In Russ.)

[2] Afanasyev A.I., Bekirov T.M., Barsuk S.D., Natural gas and condensate processing technology, Guide, v. 1, Nedra-Biznestsentr Publ., Moscow, 2002 (In Russ.)

[3] Dytnerskiy Yu.I., Brykov V.P., Kagramanov G.G., Membrane separation of gases, Khimiya Publ., Moscow, 1991 (In Russ.)

[4] Amosova O.L., Hybrid membrane-adsorption methods for separation of multicomponent gas mixtures of petrochemistry and biotechnology containing H$_2$ (He) and CO$_2$, PhD Thesis, A.V. Topchiyev Institute of Petrochemical Synthesis of RAS, 2011 (In Russ.) | Zbl

[5] Fomin V.M., Zinovyev V.N., Kazanin I.V., Lebiga V.A., i dr., Method of separation of a multicomponent vapor-gas mixture, Patent RF No 2508156. MKP B01D 53/02 (2006.01) (In Russ.)

[6] Zinov'ev V.N., Kazanin I.V., Pak A.Yu., Vereshchagin A.S., Lebiga V.A., Fomin V.M., “Permeability of hollow microspherical membranes to helium”, Journal of Engineering Physics and Thermophysics, 89:1 (2016), 25–37 | DOI

[7] Appen A.A., Chemistry of glass, Khimiya. Leningrad Branch, Leningrad, 1970 (In Russ.)

[8] Zinov'ev V.N., Kazanin I.V., Lebiga V.A., Pak A.Yu., Vereshchagin A.S., Fomin V.M., “Co-extraction of water vapor and helium from natural gas”, Thermophysics and Aeromechanics, 23:5 (2016), 741–746 (In Russ.)

[9] Vereshchagin A.S., Kazanin I.V., Zinov'ev V.N., Pak A.Yu., Lebiga V.A., Fomin V.M., “Determining the Helium permeability of microspherical membranes from the experimental time dependence of the absorption of helium by them”, Journal of Engineering Physics and Thermophysics, 92:4 (2019), 1025–1030 | DOI | MR