Numerical justification of the laboratory technique for testing of fire-extinguishing powders
Čelâbinskij fiziko-matematičeskij žurnal, Tome 9 (2024) no. 2, pp. 324-336.

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Improvement of firefighting means and methods for measuring their effectiveness are important tasks in the field of fire safety. The paper presents the results of experimental measurements of the minimum extinguishing concentration of powder mixtures that can be applied as effective explosion–suppressing barriers. Measurements of the minimum extinguishing concentration of the investigated powders were carried out using a laboratory method with their pulsed delivery to a microfire of class B using compressed air. In order to justify and assess possible errors of the mentioned laboratory method for measuring extinguishing efficiency, numerical 3D modeling of the interaction of a multiphase flow with a model combustion focus was performed. The analysis of the numerical modeling results has shown that, for the applied laboratory method, almost the entire portion of the investigated powder enters the combustion zone. Additionally, the numerical calculations indicate that under the specified experimental conditions, the particle size of the powder has no noticeable effect on their loss into the surrounding flame space. Thus, these results justified the use of the mentioned laboratory method for the comparative evaluation of fire–extinguishing powders with a wide range of dispersity. The application of this laboratory method for assessing the effectiveness of the fire–extinguishing powder allowed for the development of an optimal powder composition for explosion suppression, incorporating inert mineral particles as the main component and an additive of a chemically active potassium-containing combustion inhibitor.
Keywords: fire safety, powder extinguishing agents, minimum extinguishing concentration, potassium ferrocyanide, fire fighting.
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A. A. Chernov; A. G. Shmakov; O. P. Korobeinichev; T. A. Bolshova; V. I. Tatarenko; N. V. Petrova. Numerical justification of the laboratory technique for testing of fire-extinguishing powders. Čelâbinskij fiziko-matematičeskij žurnal, Tome 9 (2024) no. 2, pp. 324-336. http://geodesic.mathdoc.fr/item/CHFMJ_2024_9_2_a18/

[1] Laffitte P., Bouchet R., “Suppression of explosion waves in gaseous mixtures by means of fine powders”, 7th Symposium (International) on Combustion, 1959, 504–-508

[2] Kauffman C. W., Wolanski P., “Dust, hybrid and dusty detonations. Dynamics of shock waves, explosions and detonations”, Progress of AIAA, 94 (1984), 221–-239

[3] Ju Y., Law C. K., “Propagation and quenching of detonation waves in particle laden mixtures”, Combustion and Flame, 129 (2002), 356–-364 | DOI

[4] Krasnyansky M., “Prevention and suppression of explosions in gas–air and dust–air mixtures using powder aerosol–inhibitor”, Journal of Loss Prevention in the Process Industries, 19 (2006), 729–735 | DOI

[5] Yu M., Wang T., You H., An A., “A study on the effect of thermal property of powder on the gas explosion suppression”, Procedia Engineering, 26 (2011), 1035–1042 | DOI

[6] Zhang Y., Zhang J. L., Zhang B. M., Wang J. J., “A study on explosion suppression effect of No. 92 gasoline vapor–air mixture using ABC and BC dry powders”, China Safety Science Journal, 23 (2013), 53–58

[7] Luo Z., Wang T., Tian Z., Cheng F., Deng J., Zhang Y., “Experimental study on the suppression of gas explosion using the gas+solid suppressant of CO$_2$/ABC powder”, Journal of Loss Prevention in the Process Industries, 30 (2014), 61–67 | DOI

[8] Huang D., Wang X., Yang J., “Influence of particle size and heating rate on decomposition of BC dry chemical fire extinguishing powders”, Particulate Science and Technology, 33 (2015), 488–493 | DOI

[9] Jiang B., Liu Z., Tang M., Yang K., Lv P., Lin B., “Active suppression of premixed methane/air explosion propagation by non-premixed suppressant with nitrogen and ABC powder in a semi–confined duct”, Journal of Natural Gas Science and Engineering, 29 (2016), 141–149 | DOI

[10] Luo Z. M., Cheng F. M., Wang T., Deng J., Shu C. M., “Suppressive effects of silicon dioxide and diatomite powder aerosols on coal mine gas explosions in highlands”, Aerosol and Air Quality Research, 16 (2016), 21190–22128 | DOI

[11] Wang Y., Cheng Y.-S., Yu M.-G., Li Y., Cao J.-L., Zheng L.-G., Yi H.-W., “Methane explosion suppression characteristics based on the NaHCO$_3$/red mud composite powders with core–shell structure”, Journal of Hazardous Materials, 335 (2017), 84–91 | DOI

[12] Zhao T., Chen X., Cheng F., Lu K., Shi X., Yu W., “Study on the synergistic inhibition mechanism of multicomponent powders on methane explosions”, Powder Technology, 418 (2023), 118326 | DOI

[13] Babushok V., Tsang W., “Inhibitor rankings for alkane combustion”, Combustion and Flame, 123 (2000), 488–506 | DOI

[14] Jensen D. E., Jones G. A., Mace A., Christopher H., “Inhibiting the flame by a potassium”, Journal of the Chemical Society, Faraday Transactions, 10 (1979), 2377–2385 | DOI

[15] Pak V., Hieftje G. M., “Evaporation of particles of chlorides of alkaline metals in a flame”, Spectrochimical Acta, 40 (1985), 209–216 | DOI

[16] Shmakov A.G., Korobeinichev O.P., Shvartsberg V.M., Yakimov S.A., Knyazkov D.A., Komarov V.F., Sakovich G.V., “Testing ogranophosphorus, organofluorine, and metal-containing compounds and solid-propellant gas-generating compositions doped with phosphorus-containing additives as effective fire suppressants”, Combustion, Explosion and Shock Waves, 42:6 (2006), 678–687 | DOI

[17] Antsupov E.V., “Synergism and antagonism in the action of powder inhibitors in propane-air flames”, Russian Journal of Physical Chemistry B, 4:1 (2010), 75–80 | DOI

[18] Volkov V.K., Vogman L.P., Mikhaylov V.G., Golev L.B., “Laboratory device for studying the fire extinguishing effectiveness of powder compositions”, Fire equipment and fire extinguishing, v. 12, Moscow, VNIIPO Publ., 1974, 74–77 (In Russ.)

[19] Baratov A.N., Dobrikov V.V., Kulikov V.N., “Laboratory method for testing the fire extinguishing effectiveness of powders”, Flammability of substances and chemical fire extinguishing agents, v. 5, VNIIPO Publ., Moscow, 1978, 83–89 (In Russ.)

[20] Baratov A.N., Vogman L.P., Fire extinguishing powder compositions, Stroyizdat Publ., Moscow, 1982 (In Russ.)

[21] Sabinin O.Yu., “Experimental study of the influence of technological properties of powder compositions on their fire extinguishing ability in the pulsed fire extinguishing method”, Fire and explosion safety, 17:6 (2008), 64–73 (In Russ.)

[22] Misnikov O.S., Dmitriev O.V., Popov V.I., “Study of the properties of fire extinguishing powders modified with peat hydrophobic additives”, Proceedings of Instorf, 8 (2013), 23–32 (In Russ.)

[23] Korolchenko D.A., Estimation of the time of blocking evacuation routes by fire hazards in buildings and structures, taking into account the mechanism of extinguishing flames with substances of different nature and degree of dispersion, Thesis, Moscow, 2021 (In Russ.)

[24] GOST R 53280. 4–2009, Automatic fire extinguishing devices. Fire extinguishing agents. Part 4. General purpose fire extinguishing powders. General technical requirements and test methods (In Russ.)

[25] Rosser W. A., Inami S. H., Wise H., “The effect of metal salts on premixed hidrocarbon air flame”, Combustion and Flame, 7:2 (1963), 107–119 | DOI

[26] Burke R., van Tiggelen A., “Kinetics of laminar premixed methane-oxygen-nitrogen flames”, Bulletin des Socits Chimiques Belges, 74:9–10 (1965), 426–449 | DOI

[27] Baratov A.N., Combustion — fire — explosion — safety, FGU VNIIPO MChS Rossii, Moscow, 2003 (In Russ.)

[28] Shmakov A.G., Korobeinichev O.P., Shvartsberg V.M., Sidelnikov A.A., Multi-purpose fire extinguishing powder and method for its production, RF Patent No. 2719680, registration date 04/21/2020 (In Russ.)

[29] Cox G., Chittya R., “Study of the deterministic properties of unbounded fire plumes”, Combustion and Flame, 39 (1980), 191–209 | DOI