Measuring the specific heat capacity of glass based on 2B$_2$O$_3$+Bi$_2$O$_3$ in a wide temperature interval

D. S. Kuchakshoev   ; A. G. Dzhabarov   ; A. Kholov

Vestnik Ûžno-Uralʹskogo gosudarstvennogo universiteta. Seriâ, Matematika, mehanika, fizika, Tome 15 (2023) no. 3, pp. 89-96

Résumé

In this work, we used cooling to experimentally determine the temperature dependence of the specific heat capacity of glass made with the compound 2B$_2$O$_3$+Bi$_2$O$_3$ (2:1) with the addition of 0,01, 0,02, 0,04, 0,08, 0,12, and 0,5 mol NaOH to 1 mol of the initial mixture. It has been experimentally determined that with an increase in the Na content in the initial mixture, the temperature dependences of the specific heat capacity of glasses from the melt to close to room temperature are complex. Their physical interpretation is given based on the features of molecular mobility in the temperature range up to and above the glass transition temperatures.

Détail

Keywords: specific heat capacity, glass, temperature, cooling rate.

Bibliographie

[1] P. Becker, “Thermal and Optical Properties of Glasses of the System Bi$_2$O$_3$-B$_2$O$_3$”, Cryst. Res. Technol., 38:1 (2003), 74–82 | DOI

[2] Kuzmicheva G.M., Mel'nikova T.I., “Structural Features of Bismuth Borates in the System nBi$_2$O$_3$-mB$_2$O$_3$”, Russian Journal of Inorganic Chemistry, 54:1 (2009), 73–80 | DOI

[3] Yukhin Yu.M., Chemistry of Bismuth Compounds and Materials, Nauka Publ, Novosibirsk, 2001, 359 pp. (in Russ.)

[4] Denisov V.M., Belousova N.V., Moiseev G.K., Bakhvalov S.G., Istomin S.A., Pastukhov E.A., Bismuth - containing systems: structure and physico-chemical properties, UrO RAN, Ekaterinburg, 2000, 525 pp. (in Russ.)

[5] Egorysheva A.V., Volodin V.D., Skorikov V.M., “Glass Formation in the Bi$_2$O$_3$-B$_2$O$_3$-BaO System”, Inorganic Materials, 44:11 (2008), 1261–1265 | DOI

[6] Irtyugo L.A., Denisov V.M., Zhereb V.P., Denisova L.T., Babitscky N.A., “High-Temperature Heat Capacity of Bismuth Borate Glasses”, Journal of Siberian Federal University. Chemistry, 4:4 (2011), 344–349

[7] A.A. Kaminskii, P. Becker, L. Bohatý et al., “Monoclinic Bismuth Triborate BiB$_3$O$_6$ - a New Efficient $\chi(2)+\chi(3)$ - Nonlinear Crystal Multiple Stimulated Raman Scattering and Selfsum - Frequency Lasting Effects”, Optic Commun., 206:1-3 (2002), 179–191 | DOI

[8] A.V. Egorysheva, V.M. Skorikov, “Egorysheva, A.V. Efficient Nonlinear Optical Material BiB$_3$O$_6$ (BiBO)”, Inorganic Materials, 45:13 (2009), 1461–1476 | DOI

[9] F.Yu. Zavartsev, S.A. Koutovoia, V.V. Voronov et al., “Phenomenon of Metastable Liquation during BiB$_3$O$_6$ Crystallization”, Journal of Crystal Growth, 275:1-2 (2005), e637–e641 | DOI

[10] Zaytsev A.I., Vasil'ev A.D., “Phase Formation upon Crystallization of BiB$_3$O$_6$ Glasses”, Phase transitions, ordered states and new materials, 2007, 1–4

[11] R. Cong, J. Zhu, Y. Wang et al., “Phase Transitions Among Four BiB$_3$O$_6$ Polymorphs: a Detailed Investigation”, CrystEngComm, 11 (2009), 1971 | DOI

[12] R. Cong, T. Yang, J. Sun et al., “Observation of the Sixth Polymorph of BiB$_3$O$_6$: In Situ High-Pressure Raman Spectroscopy and Synchrotron Xray Diffraction Studies on the $\beta$-Polymorph”, Inorganic Chemistry, 52:13 (2013), 7460–7466 | DOI

[13] E.M. Levin, C.L. McDaniel, “The System Bi$_2$O$_3$-B$_2$O$_3$”, Journal of the American Ceramic Society, 45:8 (1962), 355–360 | DOI

[14] Zhereb V.P., Metastable States in Bismuth-Containing Oxide Systems, MAKS press Publ, M., 2003, 163 pp. (in Russ.)

[15] Kargin Yu.F., Zhereb V.P., Egorysheva A.V., “Metastable Phase Diagram for the Bi$_2$O$_3$-B$_2$O$_3$ System”, Russian Journal of Inorganic Chemistry, 47:8 (2002), 1240–1242

[16] B. Teng, J. Wang, Z. Wang et al., “Crystal Growth, Thermal and Optical Performance of BiB$_3$O$_6$”, J. Cryst. Growth, 233:1-2 (2001), 282–286 | DOI

[17] V.M. Skorikov, Yu.F. Kargin, A.V. Egorysheva et al., “Growth of Sillenite-Structure Single Crystals”, Inorganic Materials, 41, Suppl. 1 (2005), S24-S46 | DOI

[18] Zhereb V.P., Babitskiy N.A., Bermeshev T.V., Shubin A.A., Sidorak A.V., “Glass Formation in the Bi$_2$O$_3$-B$_2$O$_3$. Thermal Stability and Glass Structure”, Journal of Siberian Federal University. Chemistry, 7:3 (2014), 371–382

[19] Kuchakshoev D.S., Dzhabarov A.G., “Differential Thermal Analysis of the Binary System Bi$_2$O$_3$ + Na$_2$B$_4$O$_7$”, Reports of the National Academy of Sciences of Tajikistan, 58:12 (2015), 1096–1099

[20] Kuchakshoev, D.S., “Influence of NaOH on the Specific Heat Capacity of B$_2$O$_3$-2Bi$_2$O$_3$ System Glasses Depending on Temperature”, Polytechnic Bulletin. Series: Intelligence. Innovation. Investments, 2022, no. 3(59), 32–35

[21] Kuchakshoev D.S., Dzhabarov A.G., Kholov A., “Properties of Glasses Based on Compounds of Bi$_2$O$_3$ and Na$_2$B$_4$O$_7$”, Reports of the National Academy of Sciences of Tajikistan, 63:7-8 (2020), 488–493

[22] Kuchakshoev D.S., Dzhabarov A.G., Kholov A., “Specific Heat Capacity Determination Glasses Based on Bismuth Borates”, News of the National Academy of Sciences of Tajikistan. Department of physical, mathematical, chemical, geological and technical sciences, 2022, no. 4, 77–83

[23] Kuchakshoev D.S., Dzhabarov A.G., Kholov A., “X-ray Phase Analysis of Glasses (2Bi$_2$O$_3$-B$_2$O$_3$) and (Bi$_2$O$_3$-2B$_2$O$_3$) with Different Concentrations of NaOH in the Molding Sand”, Reports of the National Academy of Sciences of Tajikistan, 65:1-2 (2022), 69–74

[24] S.V. Nemilov, “Viscosity of Borate Glass-forming Melts: Spesific Fetures of the BO4 Tetrahedron as a Kinetic Unit”, Glass Physics and Chemistry, 23:1 (1997), 1–26

[25] D.L. Griscom, “Borate Glass Structure”, Borate Glasses. Structure, Properties, Applications, Springer Science+Business Media, New York, 1978, 11–138 | DOI