Geodesic
Structure and growth kinetics of films of adamantane in a glow discharge
Journal of Samara State Technical University, Ser. Physical and Mathematical Sciences, Tome 128 (2012) no. 3, pp. 170-179 Cet article a éte moissonné depuis la source Math-Net.Ru

Voir la notice de l'article

The peculiarities of the structure of polymers synthesized in a low-pressure glow discharge in vapors of adamantane on the electrodes and substrates at a “floating” potential are described. The structure of the product formed is conditioned by the ratio of deposits of the mechanisms of the surface and volume polymerization in the formation of the polymer on the surface. The determining factors are the type of discharge and its parameters — direct or alternating current discharge, pressure and current density, presence of the flow of gas or its absence in connection with the feed in the zone of formation of coatings and set out from her particles of the dispersed phase; the location of the substrate in the area of the discharge and outside of it. The kinetics of growth of films of adamantane at different discharge conditions on the electrodes of different materials — aluminum and copper was studied. The growth rate of polymers varied between 0.5–1.4 nm/s at the anode, and 4.2–7.5 nm/s at the cathode for different discharge modes and two electrode materials.
Keywords: discharge polymerization in vapors of adamantane, structure of polymer films, the growth kinetics of the films of adamantane. 
@article{VSGTU_2012_128_3_a16,
     author = {A. M. Shterenberg and V. I. Zsin and A. V. Shatskii and A. A. Safonov},
     title = {Structure and growth kinetics of films of adamantane in a glow discharge},
     journal = {Journal of Samara State Technical University, Ser. Physical and Mathematical Sciences},
     pages = {170--179},
     year = {2012},
     volume = {128},
     number = {3},
     language = {ru},
     url = {http://geodesic.mathdoc.fr/item/VSGTU_2012_128_3_a16/}
}
TY  - JOUR
AU  - A. M. Shterenberg
AU  - V. I. Zsin
AU  - A. V. Shatskii
AU  - A. A. Safonov
TI  - Structure and growth kinetics of films of adamantane in a glow discharge
JO  - Journal of Samara State Technical University, Ser. Physical and Mathematical Sciences
PY  - 2012
SP  - 170
EP  - 179
VL  - 128
IS  - 3
UR  - http://geodesic.mathdoc.fr/item/VSGTU_2012_128_3_a16/
LA  - ru
ID  - VSGTU_2012_128_3_a16
ER  - 
%0 Journal Article
%A A. M. Shterenberg
%A V. I. Zsin
%A A. V. Shatskii
%A A. A. Safonov
%T Structure and growth kinetics of films of adamantane in a glow discharge
%J Journal of Samara State Technical University, Ser. Physical and Mathematical Sciences
%D 2012
%P 170-179
%V 128
%N 3
%U http://geodesic.mathdoc.fr/item/VSGTU_2012_128_3_a16/
%G ru
%F VSGTU_2012_128_3_a16
A. M. Shterenberg; V. I. Zsin; A. V. Shatskii; A. A. Safonov. Structure and growth kinetics of films of adamantane in a glow discharge. Journal of Samara State Technical University, Ser. Physical and Mathematical Sciences, Tome 128 (2012) no. 3, pp. 170-179. http://geodesic.mathdoc.fr/item/VSGTU_2012_128_3_a16/

[1] Tkachuk B. V., Kolotyrkin V. M., Thin polymer film deposition from the gas phase, Khimiya, Moscow, 1977, 321 pp.

[2] Yasuda H., Plasma polymerization, Academic Press, New York, 1985, 240 pp.; Yasuda Kh.,, Polimerizatsiya v plazme, Mir, M., 1988, 376 pp.

[3] Shterenberg A. M., Potapov V. K., Macrokinetics of Dispersed-Phase Formation in Gas Discharge Systems, SamGTU, Samara, 1997, 180 pp.

[4] Fedoseev D. V., Lavrentiev A. V., Varshavskaya I. G., “Polymerization of Adamantane Vapors in Electrical Discharge”, Dokl. AN SSSR, 291:4 (1986), 917–919

[5] Dahl J. E., Carlson R. M., Liu S., Queshi W. R., Bokhari W., Bias enhanced nucleation of diamond films in a chemical vapor deposition process, US Patent Application Publication; Pub. No.: US 2006/0228479 A1; Pub. Date: Oct. 12, 2006

[6] Dahl J. E., Carlson R. M., Liu S., Nucleation of diamond films from higher diamondoids, US Patent Application Publication; Pub. No.: US 2005/0019576 A1; Pub. Date: Jan. 27, 2005

[7] Andreeva A. V., Zyn V. I., Safonov A. A., Shatsky A. V., Shterenberg A. M., “Polymerization of Adamantane Vapors in Glow Discharge”, Izvest. Samarsk. Nauchn. Centra Rossiyskoy Akademii Nauk, 13:4 (2011), 84–90 | MR

[8] Safonov A. A., The kinetics of formation and properties of nano-and microstructures of the polymers synthesized in the discharge of low pressure in the vapor adamantane, Ph.D. Thesis (Phys. Math.), Samara, 2012, 152 pp.