Geodesic
Nuclear magnetic relaxation of adsorbed liquids in porous media containing paramagnetic impurity
Učënye zapiski Kazanskogo universiteta. Seriâ Fiziko-matematičeskie nauki, Uchenye Zapiski Kazanskogo Universiteta. Seriya Fiziko-Matematicheskie Nauki, Tome 153 (2011) no. 1, pp. 48-57

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Pulse NMR was used to measure nuclear magnetic relaxation times of diethylene glycol molecules in porous Vycor glasses with a diameter of pores of 11 nm in the temperature interval of 99–342 К and of water molecules in bentonite (Dash-Salakhly deposits, Azerbaijan) at temperatures of 178–293 K. The concentration of diethylene glycol in porous glasses was close to the monolayer content of 11.1 wt %, and the water content in bentonite was kept at 22 wt %. In the range of low temperatures, spin-lattice relaxation time $T_1$ of diethylene glycol is determined by the relaxation times of an electron spin of impurity ions and the spin diffusion mechanism both in original and HCl-washed porous glasses. This work discusses nature of the strong difference in temperature dependences of relaxation times $T_1$ of diethylene glycol molecules in original and HCl-washed porous glasses. Spin-lattice relaxation of the water molecules depends on the paramagnetic ions concentration and the correlation time of the water molecular motions.
Keywords: NMR, relaxation time, porous glasses, monolayer, correlation time.
Mots-clés : bentonites 
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     author = {G. G. Pimenov and B. I. Gizatullin},
     title = {Nuclear magnetic relaxation of adsorbed liquids in porous media containing paramagnetic impurity},
     journal = {U\v{c}\"enye zapiski Kazanskogo universiteta. Seri\^a Fiziko-matemati\v{c}eskie nauki},
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     publisher = {mathdoc},
     volume = {153},
     number = {1},
     year = {2011},
     language = {ru},
     url = {http://geodesic.mathdoc.fr/item/UZKU_2011_153_1_a3/}
}
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G. G. Pimenov; B. I. Gizatullin. Nuclear magnetic relaxation of adsorbed liquids in porous media containing paramagnetic impurity. Učënye zapiski Kazanskogo universiteta. Seriâ Fiziko-matematičeskie nauki, Uchenye Zapiski Kazanskogo Universiteta. Seriya Fiziko-Matematicheskie Nauki, Tome 153 (2011) no. 1, pp. 48-57. http://geodesic.mathdoc.fr/item/UZKU_2011_153_1_a3/