A new algorithm for analysis of experimental Mössbauer spectra
Ural mathematical journal, Tome 3 (2017) no. 2, pp. 33-39
A new approach to analyze the nuclear gamma resonance (NGR) spectra is presented and justified in the paper. The algorithm successively spots the Lorentz lines in the experimental spectrum by a certain optimization procedures. In Mössbauer spectroscopy, the primary analysis is based on the representation of the transmission integral of an experimental spectrum by the sum of Lorentzians. In the general case, a number of lines and values of parameters in Lorentzians are unknown. The problem is to find them. In practice, before the experimental data processing, one elaborates a model of the Mössbauer spectrum. Such a model is usually based on some additional information. Taking into account physical restrictions, one forms the shape of the lines which are close to the normalized experimental Mössbauer spectrum. This is done by choosing the remaining free parameters of the model. However, this approach does not guarantee a proper model. A reasonable way to construct a structural NGR spectrum decomposition should be based on its model-free analysis. Some model-free methods of the NGR spectra analysis have been implemented in a number of known algorithms. Each of these methods is useful but has a limited range of application. In fact, the previously known algorithms did not react to hardly noticeable primary features of the experimental spectrum, but identify the dominant components only. In the proposed approach, the difference between the experimental spectrum and the known already determined part of the spectral structure defines the next Lorentzian. This method is effective for isolation of fine details of the spectrum, although it requires a well-elaborated algorithmic procedure presented in this paper.
Keywords:
Nuclear gamma resonance (NGR) spectra.
@article{UMJ_2017_3_2_a4,
author = {Natalia V. Baidakova and Nikolai I. Chernykh and Valerii M. Koloskov and Yurii N. Subbotin},
title = {A new algorithm for analysis of experimental {M\"ossbauer} spectra},
journal = {Ural mathematical journal},
pages = {33--39},
year = {2017},
volume = {3},
number = {2},
language = {en},
url = {http://geodesic.mathdoc.fr/item/UMJ_2017_3_2_a4/}
}
TY - JOUR AU - Natalia V. Baidakova AU - Nikolai I. Chernykh AU - Valerii M. Koloskov AU - Yurii N. Subbotin TI - A new algorithm for analysis of experimental Mössbauer spectra JO - Ural mathematical journal PY - 2017 SP - 33 EP - 39 VL - 3 IS - 2 UR - http://geodesic.mathdoc.fr/item/UMJ_2017_3_2_a4/ LA - en ID - UMJ_2017_3_2_a4 ER -
%0 Journal Article %A Natalia V. Baidakova %A Nikolai I. Chernykh %A Valerii M. Koloskov %A Yurii N. Subbotin %T A new algorithm for analysis of experimental Mössbauer spectra %J Ural mathematical journal %D 2017 %P 33-39 %V 3 %N 2 %U http://geodesic.mathdoc.fr/item/UMJ_2017_3_2_a4/ %G en %F UMJ_2017_3_2_a4
Natalia V. Baidakova; Nikolai I. Chernykh; Valerii M. Koloskov; Yurii N. Subbotin. A new algorithm for analysis of experimental Mössbauer spectra. Ural mathematical journal, Tome 3 (2017) no. 2, pp. 33-39. http://geodesic.mathdoc.fr/item/UMJ_2017_3_2_a4/
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