Geodesic
Thermodynamic functions of~a~two-component spatially homogeneous system near the critical separation point
Teoretičeskaâ i matematičeskaâ fizika, Tome 81 (1989) no. 3, pp. 455-467

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In the vicinity of critical separation point the evident expression for free energy of double component isotropic system as the function of composition, temperature and Hamiltonian initial parameters is received. With $T\geqslant T_c$ the investigated system represents homogeneous mixture. With $T\leqslant T_c$ the sphere of free energy instability according to concentration is determined in which the component stratification takes place. The expressions for entropy and specific heat are also given. 
@article{TMF_1989_81_3_a9,
     author = {O. V. Patsahan and I. R. Yukhnovskii},
     title = {Thermodynamic functions of~a~two-component spatially homogeneous system near the critical separation point},
     journal = {Teoreti\v{c}eska\^a i matemati\v{c}eska\^a fizika},
     pages = {455--467},
     publisher = {mathdoc},
     volume = {81},
     number = {3},
     year = {1989},
     language = {ru},
     url = {http://geodesic.mathdoc.fr/item/TMF_1989_81_3_a9/}
}
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O. V. Patsahan; I. R. Yukhnovskii. Thermodynamic functions of~a~two-component spatially homogeneous system near the critical separation point. Teoretičeskaâ i matematičeskaâ fizika, Tome 81 (1989) no. 3, pp. 455-467. http://geodesic.mathdoc.fr/item/TMF_1989_81_3_a9/