Geodesic
La struttura cristallina della kernite, Na2B4O6(OH)2·3 H2O
Atti della Accademia nazionale dei Lincei. Rendiconti della Classe di scienze fisiche, matematiche e naturali, Série 8, Tome 42 (1967) no. 2, pp. 236-251 Cet article a éte moissonné depuis la source Biblioteca Digitale Italiana di Matematica

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The crystal structure of kernite, Na2B4O6(OH)2·3 H2O has been determined by means of x-ray diffraction, using the Weissenberg equiinclination technique. The structure was solved from direct methods, giving the signs to 25% of the observed structure factors, and from a three-dimensional Fourier synthesis. Least squares refinement with 951 independent reflections yielded a reliability index of 0.083, based on the observed reflections only. The approximate positions of the hydrogen atoms could be deduced from stereochemical considerations. The monoclinic cell has dimensions, a = 7.022, b = 9.151, c = 15.676 Å; ß = 108.8°. The space group is P 21/c. For a cell containing four units of Na2B4O6(OH)2·3 H2O, the calculated density is 1.904 g·cm-3. The atoms within the square brackets are interconnected along the y axis so as to form an infinite chain complex [B4O6(OH)2]n-2n. Both sodium atoms coordinate five oxygens according to a distorted trigonal bipyramid. The Na(1) and Na(2) coordination polyhedra are connected by a corner, and Na(1) shares an edge with its centro-symmetrical one, to form a four-membered group. The boron-oxygen chains, two per cell, are linked three-dimensionally by the Na polyhedra groups and by hydrogen bonds. 
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     title = {La struttura cristallina della kernite, {Na2B4O6(OH)2{\textperiodcentered}3} {H2O}},
     journal = {Atti della Accademia nazionale dei Lincei. Rendiconti della Classe di scienze fisiche, matematiche e naturali},
     pages = {236--251},
     year = {1967},
     volume = {Ser. 8, 42},
     number = {2},
     language = {it},
     url = {http://geodesic.mathdoc.fr/item/RLINA_1967_8_42_2_a16/}
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Cialdi, Gloria; Corazza, Egizio; Sabelli, Cesare. La struttura cristallina della kernite, Na2B4O6(OH)2·3 H2O. Atti della Accademia nazionale dei Lincei. Rendiconti della Classe di scienze fisiche, matematiche e naturali, Série 8, Tome 42 (1967) no. 2, pp. 236-251. http://geodesic.mathdoc.fr/item/RLINA_1967_8_42_2_a16/

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