Geodesic
Kinetic characteristics of dispersion of organosilicon compounds in vacuum and molecular structure of the coatings, deposited from volatile products of dispersion
Problemy fiziki, matematiki i tehniki, no. 3 (2011), pp. 32-38.

Voir la notice de l'article provenant de la source Math-Net.Ru

It is shown that the kinetic characteristics of electron-beam dispersion of organosilicone compounds and molecular structure of the layers, deposited from the gas phase, which was formed under dispersion, are conditioned by the processes of chemical interaction, occurring in the area of electron stream towards the target. Under dispersion in plasma activation of gas phase environment the layers with lower density of hydrocarbon fragments and higher density of unsaturated bonds are formed. The possibility of the formation of highly dispersed composite coatings based on organosilicone compounds is found. The molecular structure of the organosilicone compounds has notable differences from the structure of the original components.
Keywords: organosilicone compound, electron-beam dispersion, morphology, molecular structure, composition coating. 
@article{PFMT_2011_3_a5,
     author = {M. A. Yarmolenko and A. A. Rogachev and A. V. Rogachev and D. L. Gorbochev},
     title = {Kinetic characteristics of dispersion of organosilicon compounds in vacuum and molecular structure of the coatings, deposited from volatile products of dispersion},
     journal = {Problemy fiziki, matematiki i tehniki},
     pages = {32--38},
     publisher = {mathdoc},
     number = {3},
     year = {2011},
     language = {ru},
     url = {http://geodesic.mathdoc.fr/item/PFMT_2011_3_a5/}
}
TY  - JOUR
AU  - M. A. Yarmolenko
AU  - A. A. Rogachev
AU  - A. V. Rogachev
AU  - D. L. Gorbochev
TI  - Kinetic characteristics of dispersion of organosilicon compounds in vacuum and molecular structure of the coatings, deposited from volatile products of dispersion
JO  - Problemy fiziki, matematiki i tehniki
PY  - 2011
SP  - 32
EP  - 38
IS  - 3
PB  - mathdoc
UR  - http://geodesic.mathdoc.fr/item/PFMT_2011_3_a5/
LA  - ru
ID  - PFMT_2011_3_a5
ER  - 
%0 Journal Article
%A M. A. Yarmolenko
%A A. A. Rogachev
%A A. V. Rogachev
%A D. L. Gorbochev
%T Kinetic characteristics of dispersion of organosilicon compounds in vacuum and molecular structure of the coatings, deposited from volatile products of dispersion
%J Problemy fiziki, matematiki i tehniki
%D 2011
%P 32-38
%N 3
%I mathdoc
%U http://geodesic.mathdoc.fr/item/PFMT_2011_3_a5/
%G ru
%F PFMT_2011_3_a5
M. A. Yarmolenko; A. A. Rogachev; A. V. Rogachev; D. L. Gorbochev. Kinetic characteristics of dispersion of organosilicon compounds in vacuum and molecular structure of the coatings, deposited from volatile products of dispersion. Problemy fiziki, matematiki i tehniki, no. 3 (2011), pp. 32-38. http://geodesic.mathdoc.fr/item/PFMT_2011_3_a5/

[1] B. A. Kamaritskii, Fiziko-khimicheskie osnovy sinteza oligo i poliorganosilseskvioksanov, Dis. ... d-ra khim. nauk: 02.00.04, IKhF AN BSSR, M., 1989

[2] A. M. Tonshin, B. A. Kamaritskii, V. N. Spektor, “Tekhnologiya, stroenie i svoistva kremniiorganicheskikh dielektrikov — poliorganosilseskvioksanov”, Uspekhi khimii, 52 (1983), 1365–1409

[3] B. V. Tkachuk, V. M. Kolotyrkin, Poluchenie tonkikh polimernykh plenok iz gazovoi fazy, Khimiya, M., 1977, 216 pp.

[4] V. P. Kazachenko, Kinetika elektronno-luchevogo dispergirovaniya polimerov v vakuume, struktura, svoistva pokrytii, poluchennykh osazhdeniem letuchikh produktov, Avtoref. dis. ... kand. fiz.-mat. nauk: 02.00.04, NIFKhI, M., 1992, 26 pp.

[5] A. I. Egorov, Fiziko-khimicheskie zakonomernosti protsessov massoperenosa pri plazmo-khimicheskom okrashivanii i appretirovanii polietilentereftalata, Avtoref. dis. ... kand. tekhn. nauk: 01.04.19, IMMS NANB, Gomel, 1999, 22 pp.

[6] V. P. Kazachenko, A. V. Rogachev, “Zakonomernosti dispergirovaniya politetraftoretilena potokom elektronov srednikh energii”, Khimiya vysokikh energii, 33:4 (1999), 270–273

[7] L. Bellami, Infrakrasnye spektry slozhnykh molekul, Mir, M., 1963, 592 pp.

[8] L. A. Kazitsyna, N. B. Kupletskaya, Primenenie UF-, IK- i YaMR-spektroskopii v organicheskoi khimii, Ucheb. posobie dlya vuzov, Vyssh. shkola, M., 1971, 264 pp.

[9] I. L. Knunyants i dr. (red.), Khimicheskaya entsiklopediya, v 5 t., v. 2, Daffa-Medi, Sov. entsikl., M., 1990, 671 pp.