Geodesic
The effect of Ag(0) colloidal crystals and nanoribbons formation as a result of the redox reaction between Ce(III) and Ag(I) cations occurring on the surface of an aqueous solution of their salts mixture
Nanosistemy: fizika, himiâ, matematika, Tome 15 (2024) no. 1, pp. 98-103.

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The proposed study shows for the first time that gaseous ammonia treatment of AgNO$_3$ and Ce(NO$_3$)$_3$ salts mixture aqueous solution surface gives rise to formation of a composite layer consisting of Ag(0) faceted colloidal crystals and nanoribbons, as well as CeO$_2$ nanocrystals. A study of such a composite carried out by FESEM, XRD, EDX, TEM, STEM and HRTEM methods has shown that the nanoribbons are about 50–150 nm wide and up to 2–3 $\mu$m long, and that there are 2–3 nm CeO$_2$ nanocrystals on the surface thereof. Colloidal crystals of about several micrometers consist of separate, almost identical silver nanocrystals about 20 nm in size. The obtained results provided a basis for construction of schemes of chemical reactions taking place during the synthesis, and gave grounds for recommendations on practical application of the obtained compounds.
Keywords: silver, colloidal crystals, nanoribbons, CeO$_2$, interface synthesis.
Mots-clés : composite 
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     author = {Valeri P. Tolstoy and Evelina E. Shilovskikh and Larisa B. Gulina},
     title = {The effect of {Ag(0)} colloidal crystals and nanoribbons formation as a result of the redox reaction between {Ce(III)} and {Ag(I)} cations occurring on the surface of an aqueous solution of their salts mixture},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
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Valeri P. Tolstoy; Evelina E. Shilovskikh; Larisa B. Gulina. The effect of Ag(0) colloidal crystals and nanoribbons formation as a result of the redox reaction between Ce(III) and Ag(I) cations occurring on the surface of an aqueous solution of their salts mixture. Nanosistemy: fizika, himiâ, matematika, Tome 15 (2024) no. 1, pp. 98-103. http://geodesic.mathdoc.fr/item/NANO_2024_15_1_a10/