Geodesic
Synthesis and thermal behavior of KCe$_2$(PO$_4$)$_3$, a new full-member in the A$^{\mathrm{I}}$M$^{\mathrm{IV}}_2$(PO$_4$)$_3$ family
Nanosistemy: fizika, himiâ, matematika, Tome 14 (2023) no. 1, pp. 112-119.

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Hydrothermal treatment of nanoscale amorphous ceric phosphate gel in KOH aqueous solutions was found to result in a new KCe$_2$(PO$_4$)$_3$ phase. The refinement of the KCe$_2$(PO$_4$)$_3$ structure showed that it was isostructural to recently reported (NH$_4$)Ce$_2$(PO$_4$)$_3$. For the KCe$_2$(PO$_4$)$_3$ phase, the unit cell parameters (sp. gr. $C2/c$) were $a$ = 17.3781(3)$\mathring{\mathrm{A}}$, $b$ = 6.7287(1)$\mathring{\mathrm{A}}$, $c$ = 7.9711(2)$\mathring{\mathrm{A}}$, $\beta$= 102.351(1)$^\circ$, $V$ = 910.53(4)$\mathring{\mathrm{A}}^3$, $Z$ = 4. The thermal decomposition of KCe$_2$(PO$_4$)$_3$ at 800$^\circ$C resulted in the mixture of crystalline CePO$_4$ and KPO$_3$.
Keywords: cerium, potassium, channel, hydrothermal.
Mots-clés : polyphosphate 
@article{NANO_2023_14_1_a13,
     author = {Taisiya O. Kozlova and Darya N. Vasilyeva and Daniil A. Kozlov and Mariia A. Teplonogova and Alexander Y. Baranchikov and Nikolay P. Simonenko and Vladimir K. Ivanov},
     title = {Synthesis and thermal behavior of {KCe}$_2${(PO}$_4$)$_3$, a new full-member in the {A}$^{\mathrm{I}}${M}$^{\mathrm{IV}}_2${(PO}$_4$)$_3$ family},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {112--119},
     publisher = {mathdoc},
     volume = {14},
     number = {1},
     year = {2023},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2023_14_1_a13/}
}
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AU  - Nikolay P. Simonenko
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%A Mariia A. Teplonogova
%A Alexander Y. Baranchikov
%A Nikolay P. Simonenko
%A Vladimir K. Ivanov
%T Synthesis and thermal behavior of KCe$_2$(PO$_4$)$_3$, a new full-member in the A$^{\mathrm{I}}$M$^{\mathrm{IV}}_2$(PO$_4$)$_3$ family
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Taisiya O. Kozlova; Darya N. Vasilyeva; Daniil A. Kozlov; Mariia A. Teplonogova; Alexander Y. Baranchikov; Nikolay P. Simonenko; Vladimir K. Ivanov. Synthesis and thermal behavior of KCe$_2$(PO$_4$)$_3$, a new full-member in the A$^{\mathrm{I}}$M$^{\mathrm{IV}}_2$(PO$_4$)$_3$ family. Nanosistemy: fizika, himiâ, matematika, Tome 14 (2023) no. 1, pp. 112-119. http://geodesic.mathdoc.fr/item/NANO_2023_14_1_a13/