Geodesic
Polymer nanocarbon materials as ion-to-electron transducers in solid-contact ion-selective electrodes
Nanosistemy: fizika, himiâ, matematika, Tome 13 (2022) no. 6, pp. 688-697.

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Carbon nanoparticles materials in polymer modification have gained particular importance in modern potentiometric studies after they were discovered to be ion-to-electron transducers in solid-contact ion-selective electrodes (SC-ISEs). This paper describes the preparation and comparative evaluation of poly(vinyl chloride) (PVC) and Nafion membranes incorporated with light fullerene C60, single carbon nanotubes (SWC-NTs) and their mixture as transducer interlayers in the SC-ISE based on the ion-sensing PVC-membrane containing a high lipophilic 2-[bis-octadecyl sulfonic)-closo-decaborate anion. The best electroanalytical performance was achieved for the sensor fabricated with the transducer made by combining two transducing layers, a Nafion film modified with fullerene C60 and a plasticized PVC film modified with SWCNTs-C60 hybrid filler, which were sequentially applied onto the substrate carbositall electrode surface. The test results showed that the newly prepared a layer-by-layer SC-ISE is suitable for the sensitive determination of local anesthetics and some other protonable nitrogen-containing drugs.
Keywords: nanocarbon-doped polymers, fullerene C60/SWCNTs, solid-contact ion-selective electrode, ion-to-electron transducing materials, local anesthetics. 
@article{NANO_2022_13_6_a12,
     author = {Konstantin Yu. Zhizhin and Evgeniy S. Turyshev and Aleksander V. Kopytin and Liliya K. Shpigun and Nikolay T. Kuznetsov and Nikolay P. Simonenko and Natalya N. Zamyatina and Mukhammadislom S. Madraimov and Gbeb I. Betenev},
     title = {Polymer nanocarbon materials as ion-to-electron transducers in solid-contact ion-selective electrodes},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {688--697},
     publisher = {mathdoc},
     volume = {13},
     number = {6},
     year = {2022},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2022_13_6_a12/}
}
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AU  - Evgeniy S. Turyshev
AU  - Aleksander V. Kopytin
AU  - Liliya K. Shpigun
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AU  - Nikolay P. Simonenko
AU  - Natalya N. Zamyatina
AU  - Mukhammadislom S. Madraimov
AU  - Gbeb I. Betenev
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%0 Journal Article
%A Konstantin Yu. Zhizhin
%A Evgeniy S. Turyshev
%A Aleksander V. Kopytin
%A Liliya K. Shpigun
%A Nikolay T. Kuznetsov
%A Nikolay P. Simonenko
%A Natalya N. Zamyatina
%A Mukhammadislom S. Madraimov
%A Gbeb I. Betenev
%T Polymer nanocarbon materials as ion-to-electron transducers in solid-contact ion-selective electrodes
%J Nanosistemy: fizika, himiâ, matematika
%D 2022
%P 688-697
%V 13
%N 6
%I mathdoc
%U http://geodesic.mathdoc.fr/item/NANO_2022_13_6_a12/
%G en
%F NANO_2022_13_6_a12
Konstantin Yu. Zhizhin; Evgeniy S. Turyshev; Aleksander V. Kopytin; Liliya K. Shpigun; Nikolay T. Kuznetsov; Nikolay P. Simonenko; Natalya N. Zamyatina; Mukhammadislom S. Madraimov; Gbeb I. Betenev. Polymer nanocarbon materials as ion-to-electron transducers in solid-contact ion-selective electrodes. Nanosistemy: fizika, himiâ, matematika, Tome 13 (2022) no. 6, pp. 688-697. http://geodesic.mathdoc.fr/item/NANO_2022_13_6_a12/