Geodesic
Layer-by-layer synthesis of Zn-doped MnO$_2$ nanocrystals as cathode materials for aqueous zinc-ion battery
Nanosistemy: fizika, himiâ, matematika, Tome 12 (2021) no. 2, pp. 182-187.

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This work first described the new oxidation-reduction route for the synthesis of Zn-doped MnO$_2$nanocrystals via layer-by-layer method as cathode material for an aqueous zinc-ion battery. The obtained nanolayers were characterized by SEM, XRD, XPS and FTIR spectroscopy. The results show the synthesized nanolayers were formed from two-dimensional nanocrystals Zn$_{0.3}$MnO$_2$ the thickness of about 3–8 nm and the morphology of “nanosheets” with the birnessite-like crystal structure. Benefiting from the aqueous 2M ZnSO$_4$ electrolyte and Zn$_{0.3}$MnO$_2$ nanocrystals-based cathode, the zinc-ion battery delivers a high specific capacity (216 mAh/g at 1 A/g) and excellent cycling stability (95% capacity retention after 1000 charge-discharge cycles). The obtained results demonstrate the manganese oxide-based aqueous zinc-ion battery is a promising technology for powering next-generation electronics.
Keywords: Manganese oxide, zinc, nanocrystals, layer-by-layer, electrode materials, zinc-ion battery. 
@article{NANO_2021_12_2_a7,
     author = {A. A. Lobinsky and M. V. Kaneva},
     title = {Layer-by-layer synthesis of {Zn-doped} {MnO}$_2$ nanocrystals as cathode materials for aqueous zinc-ion battery},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {182--187},
     publisher = {mathdoc},
     volume = {12},
     number = {2},
     year = {2021},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2021_12_2_a7/}
}
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A. A. Lobinsky; M. V. Kaneva. Layer-by-layer synthesis of Zn-doped MnO$_2$ nanocrystals as cathode materials for aqueous zinc-ion battery. Nanosistemy: fizika, himiâ, matematika, Tome 12 (2021) no. 2, pp. 182-187. http://geodesic.mathdoc.fr/item/NANO_2021_12_2_a7/