Supercritical fluid synthesis and possible properties of “cubic graphite”
Nanosistemy: fizika, himiâ, matematika, Tome 11 (2020) no. 4, pp. 408-416
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We report on supercritical fluid synthesis of an intermediate carbon phase–austite–at a pressure of 180 MPa and temperatures 500-700$^\circ$C from soot as a precursor and supercritical carbon dioxide as a solvent. According to the results of electron and X-ray diffractions, spectral measurements and density-functional theory calculations, the observed carbon phase is proved to be cubic with a lattice parameter value of 8.96 $\pm$ 0.05 Å and a possible structural type as for KFI zeolite.
Keywords:
crystal growth, carbon allotropes, electron microscopy, DFT calculations.
Mots-clés : X-ray diffraction
Mots-clés : X-ray diffraction
@article{NANO_2020_11_4_a4,
author = {A. V. Pokropivny and A. N. Enyashin and A. S. Smolyar and V. A. Kuts and V. G. Gurin and S. A. Antipov and P. M. Silenko and Yu. M. Solonin},
title = {Supercritical fluid synthesis and possible properties of {\textquotedblleft}cubic graphite{\textquotedblright}},
journal = {Nanosistemy: fizika, himi\^a, matematika},
pages = {408--416},
year = {2020},
volume = {11},
number = {4},
language = {en},
url = {http://geodesic.mathdoc.fr/item/NANO_2020_11_4_a4/}
}
TY - JOUR AU - A. V. Pokropivny AU - A. N. Enyashin AU - A. S. Smolyar AU - V. A. Kuts AU - V. G. Gurin AU - S. A. Antipov AU - P. M. Silenko AU - Yu. M. Solonin TI - Supercritical fluid synthesis and possible properties of “cubic graphite” JO - Nanosistemy: fizika, himiâ, matematika PY - 2020 SP - 408 EP - 416 VL - 11 IS - 4 UR - http://geodesic.mathdoc.fr/item/NANO_2020_11_4_a4/ LA - en ID - NANO_2020_11_4_a4 ER -
%0 Journal Article %A A. V. Pokropivny %A A. N. Enyashin %A A. S. Smolyar %A V. A. Kuts %A V. G. Gurin %A S. A. Antipov %A P. M. Silenko %A Yu. M. Solonin %T Supercritical fluid synthesis and possible properties of “cubic graphite” %J Nanosistemy: fizika, himiâ, matematika %D 2020 %P 408-416 %V 11 %N 4 %U http://geodesic.mathdoc.fr/item/NANO_2020_11_4_a4/ %G en %F NANO_2020_11_4_a4
A. V. Pokropivny; A. N. Enyashin; A. S. Smolyar; V. A. Kuts; V. G. Gurin; S. A. Antipov; P. M. Silenko; Yu. M. Solonin. Supercritical fluid synthesis and possible properties of “cubic graphite”. Nanosistemy: fizika, himiâ, matematika, Tome 11 (2020) no. 4, pp. 408-416. http://geodesic.mathdoc.fr/item/NANO_2020_11_4_a4/