Formation mechanism of core-shell nanocrystals obtained via dehydration of coprecipitated hydroxides at hydrothermal conditions
Nanosistemy: fizika, himiâ, matematika, Tome 9 (2018) no. 4, pp. 568-572
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Here, we propose a formation mechanism for core-shell nanoparticles by self-organization in coprecipitated mixed hydroxides under hydrothermal conditions. A thermodynamic reason for this process is because of a decrease in the components’ solubilities together with an increase of structure's dimension. As a particular example of such type of behavior, we investigate core-shell nanoparticle formation in the ZrO$_2$-Y$_2$O$_3$-H$_2$O system.
Keywords:
hydrothermal synthesis, multi-component systems, zirconia, formation mechanism.
Mots-clés : core-shell nanoparticles, solid solution
Mots-clés : core-shell nanoparticles, solid solution
@article{NANO_2018_9_4_a17,
author = {O. V. Almjasheva and A. A. Krasilin and V. V. Gusarov},
title = {Formation mechanism of core-shell nanocrystals obtained via dehydration of coprecipitated hydroxides at hydrothermal conditions},
journal = {Nanosistemy: fizika, himi\^a, matematika},
pages = {568--572},
year = {2018},
volume = {9},
number = {4},
language = {en},
url = {http://geodesic.mathdoc.fr/item/NANO_2018_9_4_a17/}
}
TY - JOUR AU - O. V. Almjasheva AU - A. A. Krasilin AU - V. V. Gusarov TI - Formation mechanism of core-shell nanocrystals obtained via dehydration of coprecipitated hydroxides at hydrothermal conditions JO - Nanosistemy: fizika, himiâ, matematika PY - 2018 SP - 568 EP - 572 VL - 9 IS - 4 UR - http://geodesic.mathdoc.fr/item/NANO_2018_9_4_a17/ LA - en ID - NANO_2018_9_4_a17 ER -
%0 Journal Article %A O. V. Almjasheva %A A. A. Krasilin %A V. V. Gusarov %T Formation mechanism of core-shell nanocrystals obtained via dehydration of coprecipitated hydroxides at hydrothermal conditions %J Nanosistemy: fizika, himiâ, matematika %D 2018 %P 568-572 %V 9 %N 4 %U http://geodesic.mathdoc.fr/item/NANO_2018_9_4_a17/ %G en %F NANO_2018_9_4_a17
O. V. Almjasheva; A. A. Krasilin; V. V. Gusarov. Formation mechanism of core-shell nanocrystals obtained via dehydration of coprecipitated hydroxides at hydrothermal conditions. Nanosistemy: fizika, himiâ, matematika, Tome 9 (2018) no. 4, pp. 568-572. http://geodesic.mathdoc.fr/item/NANO_2018_9_4_a17/