Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers
Nanosistemy: fizika, himiâ, matematika, Tome 9 (2018) no. 1, pp. 29-32
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The decomposition kinetics of the fullerene dimers and photo-oligomers was studied at elevated temperature by Raman scattering. The polymeric content decreases exponentially with the thermal treatment time while the decay time constant decreases at higher temperatures. The activation-type behavior is well described by the Arrhenius law that gives the activation energy E$_A$ = (1.71 $\pm$ 0.06) eV/molecule for the dimers and E$_A$ = (0.87 $\pm$ 0.06) eV/molecule for the C$_{60}$ photopolymer.
Keywords:
fullerene polymers, Raman spectroscopy, decomposition kinetics.
@article{NANO_2018_9_1_a4,
author = {K. P. Meletov and J. Arvanitidis and D. Christofilos and G. Kourouklis and V. A. Davydov},
title = {Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers},
journal = {Nanosistemy: fizika, himi\^a, matematika},
pages = {29--32},
publisher = {mathdoc},
volume = {9},
number = {1},
year = {2018},
language = {en},
url = {http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a4/}
}
TY - JOUR AU - K. P. Meletov AU - J. Arvanitidis AU - D. Christofilos AU - G. Kourouklis AU - V. A. Davydov TI - Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers JO - Nanosistemy: fizika, himiâ, matematika PY - 2018 SP - 29 EP - 32 VL - 9 IS - 1 PB - mathdoc UR - http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a4/ LA - en ID - NANO_2018_9_1_a4 ER -
%0 Journal Article %A K. P. Meletov %A J. Arvanitidis %A D. Christofilos %A G. Kourouklis %A V. A. Davydov %T Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers %J Nanosistemy: fizika, himiâ, matematika %D 2018 %P 29-32 %V 9 %N 1 %I mathdoc %U http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a4/ %G en %F NANO_2018_9_1_a4
K. P. Meletov; J. Arvanitidis; D. Christofilos; G. Kourouklis; V. A. Davydov. Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers. Nanosistemy: fizika, himiâ, matematika, Tome 9 (2018) no. 1, pp. 29-32. http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a4/