High pressure photoluminescence studies of diamond with GeV centers
Nanosistemy: fizika, himiâ, matematika, Tome 9 (2018) no. 1, pp. 67-69
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We report low temperature (80 K) photoluminescence studies of microcrystalline diamond with germanium-vacancy (GeV) centers under hydrostatic pressure up to 6 GPa. Powders of Ge-doped diamond crystals were synthesized from hydrocarbons at high-pressures and high-temperatures. Due to the high quality of the samples, we were able to resolve the distinct quadruplet structure of the zero-phonon line (ZPL) of the GeV center already at 80 K and to trace it up to $\sim$ 6 GPa. The pressure dependence of ZPL was found to be linear with the pressure coefficient $dE/dP$ = 3.1 meV/GPa, which is nearly 3 times higher than that for the isomorphic SiV$^-$ center. The experimentally observed pressure coefficients of GeV$^-$, NV$^-$ and NV$^0$ centers are compared with results of ab initio DFT calculations, using Quantum ESPRESSO software package.
Keywords:
diamond, colour centers, high pressure
Mots-clés : DAC.
Mots-clés : DAC.
@article{NANO_2018_9_1_a15,
author = {S. G. Lyapin and A. A. Razgulov and A. P. Novikov and E. A. Ekimov and M. V. Kondrin},
title = {High pressure photoluminescence studies of diamond with {GeV} centers},
journal = {Nanosistemy: fizika, himi\^a, matematika},
pages = {67--69},
publisher = {mathdoc},
volume = {9},
number = {1},
year = {2018},
language = {en},
url = {http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a15/}
}
TY - JOUR AU - S. G. Lyapin AU - A. A. Razgulov AU - A. P. Novikov AU - E. A. Ekimov AU - M. V. Kondrin TI - High pressure photoluminescence studies of diamond with GeV centers JO - Nanosistemy: fizika, himiâ, matematika PY - 2018 SP - 67 EP - 69 VL - 9 IS - 1 PB - mathdoc UR - http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a15/ LA - en ID - NANO_2018_9_1_a15 ER -
%0 Journal Article %A S. G. Lyapin %A A. A. Razgulov %A A. P. Novikov %A E. A. Ekimov %A M. V. Kondrin %T High pressure photoluminescence studies of diamond with GeV centers %J Nanosistemy: fizika, himiâ, matematika %D 2018 %P 67-69 %V 9 %N 1 %I mathdoc %U http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a15/ %G en %F NANO_2018_9_1_a15
S. G. Lyapin; A. A. Razgulov; A. P. Novikov; E. A. Ekimov; M. V. Kondrin. High pressure photoluminescence studies of diamond with GeV centers. Nanosistemy: fizika, himiâ, matematika, Tome 9 (2018) no. 1, pp. 67-69. http://geodesic.mathdoc.fr/item/NANO_2018_9_1_a15/