Synthesis of CaF$_2$–YF$_3$ nanopowders by co-precipitation from aqueos solutions
Nanosistemy: fizika, himiâ, matematika, Tome 8 (2017) no. 4, pp. 462-470
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Study of the CaF$_2$–YF$_3$ system by co-precipitation from aqueous nitrate solutions revealed the formation of Ca$_{1-x}$Y$_x$F$_{2+x}$ solid solution precipitate containing up to 20 mol. % yttrium fluoride (x $\le$ 0.2). A higher yttrium to calcium ratio in the starting solutions caused additional precipitation of orthorhombic $\beta$-YF$_3$ nanophase elongated along the $\langle b\rangle$ axis. Cubic (H$_3$O)Y$_3$F$_{10}$ phase was also formed (SSG $Fm3m$, $\alpha$=11.60 $\mathring{\mathrm{A}}$, KY$_3$F$_{10}$ structural type).
Keywords:
calcium fluoride, yttrium fluoride, nanopowders.
@article{NANO_2017_8_4_a7,
author = {P. P. Fedorov and M. N. Mayakova and S. V. Kuznetsov and V. V. Voronov and Yu. A. Ermakova and A. Y. Baranchikov},
title = {Synthesis of {CaF}$_2${{\textendash}YF}$_3$ nanopowders by co-precipitation from aqueos solutions},
journal = {Nanosistemy: fizika, himi\^a, matematika},
pages = {462--470},
year = {2017},
volume = {8},
number = {4},
language = {en},
url = {http://geodesic.mathdoc.fr/item/NANO_2017_8_4_a7/}
}
TY - JOUR AU - P. P. Fedorov AU - M. N. Mayakova AU - S. V. Kuznetsov AU - V. V. Voronov AU - Yu. A. Ermakova AU - A. Y. Baranchikov TI - Synthesis of CaF$_2$–YF$_3$ nanopowders by co-precipitation from aqueos solutions JO - Nanosistemy: fizika, himiâ, matematika PY - 2017 SP - 462 EP - 470 VL - 8 IS - 4 UR - http://geodesic.mathdoc.fr/item/NANO_2017_8_4_a7/ LA - en ID - NANO_2017_8_4_a7 ER -
%0 Journal Article %A P. P. Fedorov %A M. N. Mayakova %A S. V. Kuznetsov %A V. V. Voronov %A Yu. A. Ermakova %A A. Y. Baranchikov %T Synthesis of CaF$_2$–YF$_3$ nanopowders by co-precipitation from aqueos solutions %J Nanosistemy: fizika, himiâ, matematika %D 2017 %P 462-470 %V 8 %N 4 %U http://geodesic.mathdoc.fr/item/NANO_2017_8_4_a7/ %G en %F NANO_2017_8_4_a7
P. P. Fedorov; M. N. Mayakova; S. V. Kuznetsov; V. V. Voronov; Yu. A. Ermakova; A. Y. Baranchikov. Synthesis of CaF$_2$–YF$_3$ nanopowders by co-precipitation from aqueos solutions. Nanosistemy: fizika, himiâ, matematika, Tome 8 (2017) no. 4, pp. 462-470. http://geodesic.mathdoc.fr/item/NANO_2017_8_4_a7/