Geodesic
Pressure-assisted photopolymerization in the molecular donor-acceptor fullerene complex $\{\operatorname{Cd}(\operatorname{dedtc})_2\}_2\cdot\mathrm{C}_{60}$
Nanosistemy: fizika, himiâ, matematika, Tome 7 (2016) no. 1, pp. 133-139.

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The pressure-assisted photopolymerization in the fullerene complex $\{\operatorname{Cd}(\operatorname{dedtc})_2\}_2\cdot\mathrm{C}_{60}$ (fullerene complex with cadmium diethyldithiocarbamate) observed in the pressure region between $2.24$ and $5.99$ GPa was studied in detail. After a phase transition near $\sim2$ GPa, the Raman spectra exhibit time-dependent changes under prolonged laser illumination regarding the appearance of new peaks in the frequency region of the $A_g(2)$ mode of the $\mathrm{C}_{60}$ monomer. These peaks are related to the fullerene oligomers with a different number of $sp^3$-like coordinated carbon atoms per molecular cage. The polymer content increases with the laser power density and exposure time, while for a fixed laser power, its saturated value is independent of pressure. Outside the pressure range $2.24$ – $5.99$ GPa, photopolymerization is suppressed.
Keywords: high pressure, fullerene, molecular complexes, Raman scattering, photopolymerization. 
@article{NANO_2016_7_1_a17,
     author = {K. P. Meletov and J. Arvanitidis and D. Christofilos and G. Kourouklis},
     title = {Pressure-assisted photopolymerization in the molecular donor-acceptor fullerene complex $\{\operatorname{Cd}(\operatorname{dedtc})_2\}_2\cdot\mathrm{C}_{60}$},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {133--139},
     publisher = {mathdoc},
     volume = {7},
     number = {1},
     year = {2016},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2016_7_1_a17/}
}
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K. P. Meletov; J. Arvanitidis; D. Christofilos; G. Kourouklis. Pressure-assisted photopolymerization in the molecular donor-acceptor fullerene complex $\{\operatorname{Cd}(\operatorname{dedtc})_2\}_2\cdot\mathrm{C}_{60}$. Nanosistemy: fizika, himiâ, matematika, Tome 7 (2016) no. 1, pp. 133-139. http://geodesic.mathdoc.fr/item/NANO_2016_7_1_a17/