Dependence of the dimension of the associates of water-soluble tris-malonate of light fullerene -- C$_{60}$ [= C(COOH)$_2$]$_3$ in water solutions at 25$^{\circ}$C
Nanosistemy: fizika, himiâ, matematika, Tome 6 (2015) no. 2, pp. 294-298.

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Investigation of the concentration dependence of the size and type C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ aggregation in aqueous solutions at 25$^{\circ}$C was accomplished with the help of a dynamic light scattering method. It was determined that three types of aggregates are realized in the solutions. The average number of C$_{60}$ [= C(COOH)$_2$]$_3$ molecules in smaller aggregates and all types of aggregates were calculated. One can see that over the whole concentration range, from 0.01 to 10 g/dm$^{3}$, aqueous solutions of C$_{60}$ [= C(COOH)$_2$]$_3$ are characterized by sub-micro-heterogeneous behavior (because second-type aggregates with the linear dimensions - hundreds of nm are formed in all solutions). Additionally, the most concentrated solution (C = 10 g/dm$^{3}$) is characterized by micro-heterogeneous or colloid behavior (because third-type aggregates with the linear dimensions on the order of $\mu$m – are formed). In order to describe or explain such behavior, a stepwise aggregation model was invoked.
Keywords: tris-malonate of light fullerene, method of the dynamic light scattering.
@article{NANO_2015_6_2_a15,
     author = {K. N. Semenov and N. A. Charykov and A. S. Kritchenkov and I. A. Cherepkova and O. S. Manyakina and D. P. Tyurin and A. A. Shestopalova and V. A. Keskinov and K. V. Ivanova and N. M. Ivanova and D. G. Letenko and V. A. Nikitin and E. L. Fokina and M. S. Gutenev},
     title = {Dependence of the dimension of the associates of water-soluble tris-malonate of light fullerene -- {C}$_{60}$ [= {C(COOH)}$_2$]$_3$ in water solutions at 25$^{\circ}${C}},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {294--298},
     publisher = {mathdoc},
     volume = {6},
     number = {2},
     year = {2015},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2015_6_2_a15/}
}
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%A V. A. Nikitin
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K. N. Semenov; N. A. Charykov; A. S. Kritchenkov; I. A. Cherepkova; O. S. Manyakina; D. P. Tyurin; A. A. Shestopalova; V. A. Keskinov; K. V. Ivanova; N. M. Ivanova; D. G. Letenko; V. A. Nikitin; E. L. Fokina; M. S. Gutenev. Dependence of the dimension of the associates of water-soluble tris-malonate of light fullerene -- C$_{60}$ [= C(COOH)$_2$]$_3$ in water solutions at 25$^{\circ}$C. Nanosistemy: fizika, himiâ, matematika, Tome 6 (2015) no. 2, pp. 294-298. http://geodesic.mathdoc.fr/item/NANO_2015_6_2_a15/