Nanocatalysis: hypothesis on the action mechanism of gold
Nanosistemy: fizika, himiâ, matematika, Tome 6 (2015) no. 2, pp. 249-261
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In this article, the problem of nanocatalysis is considered when the catalysts are gold nanoparticles. The main experimental facts are presented and basic qualitative dependences are highlighted. The hypothesis considers the role of Tamm states of gold nanoparticles, with the modification of these states to reduce nanoparticle sizes. A semi-quantitative quantum-chemical reaction scheme of oxygen dissociation with gold nanocatalysis is shown. A theoretical answer to the basic experimental test has been obtained.
Keywords:
nanocatalysis, d-atoms, Tamm levels.
@article{NANO_2015_6_2_a10,
author = {B. L. Oksengendler and B. Askarov and I. N. Nurgaliyev and S. E. Maksimov and V. N. Nikiforov},
title = {Nanocatalysis: hypothesis on the action mechanism of gold},
journal = {Nanosistemy: fizika, himi\^a, matematika},
pages = {249--261},
year = {2015},
volume = {6},
number = {2},
language = {en},
url = {http://geodesic.mathdoc.fr/item/NANO_2015_6_2_a10/}
}
TY - JOUR AU - B. L. Oksengendler AU - B. Askarov AU - I. N. Nurgaliyev AU - S. E. Maksimov AU - V. N. Nikiforov TI - Nanocatalysis: hypothesis on the action mechanism of gold JO - Nanosistemy: fizika, himiâ, matematika PY - 2015 SP - 249 EP - 261 VL - 6 IS - 2 UR - http://geodesic.mathdoc.fr/item/NANO_2015_6_2_a10/ LA - en ID - NANO_2015_6_2_a10 ER -
%0 Journal Article %A B. L. Oksengendler %A B. Askarov %A I. N. Nurgaliyev %A S. E. Maksimov %A V. N. Nikiforov %T Nanocatalysis: hypothesis on the action mechanism of gold %J Nanosistemy: fizika, himiâ, matematika %D 2015 %P 249-261 %V 6 %N 2 %U http://geodesic.mathdoc.fr/item/NANO_2015_6_2_a10/ %G en %F NANO_2015_6_2_a10
B. L. Oksengendler; B. Askarov; I. N. Nurgaliyev; S. E. Maksimov; V. N. Nikiforov. Nanocatalysis: hypothesis on the action mechanism of gold. Nanosistemy: fizika, himiâ, matematika, Tome 6 (2015) no. 2, pp. 249-261. http://geodesic.mathdoc.fr/item/NANO_2015_6_2_a10/