Geodesic
New route to poly (2,6-diimidaazo(4,5-b: 4',5'-e) pyridinelene-1,4(2,5-dihydroxy)-phenylene) (PIPD) and high modulus fiber on it basis
Nanosistemy: fizika, himiâ, matematika, Tome 5 (2014) no. 6, pp. 829-835 Cet article a éte moissonné depuis la source Math-Net.Ru

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A novel entry toward poly(2,6-diimidazo(4,5-b: 4',5'-e) pyridinylene-1,4(2,5-dihydroxy)-phenylene) (PIPD) has been elaborated. A strategy based on a new route to monomers: a sequential nitration of 2,6-diaminopyridine with KNO$_{3}$/H$_{2}$SO$_{4}$ gives 2,6-diamino-3,5-dinitro pyridine (DNDAP) in moderate yield and its hydrogenation with Raney nickel as catalyst leads to 2,3,5,6-tetraaminopyridine (TAP) in high yield. The second monomer 2,5-dihydroxyterephthalate (DHTA) was synthesized in high yield as product of sulfurmediated aromatization of dimethyl succinoyl succinate with subsequent base hydrolysis. PIPD was synthesized by step-by-step heating in polyphosphoric acid with molecular weights of 19 – 25 kilodaltons. The macromolecule of PIPD can be seen as lap-join chain form nanosized rigid fragment. The as-polymerized liquid crystalline PIPD solution was used for fiber spinning. The tensile strength of PIPD fibers were 1.28 – 1.99 GPa and depended on the molecular weight of the polymer used for spinning.
Keywords: nano-sized rigid polymer, synthesis, fiber spinning, mechanical properties, liquid crystallinity. 
@article{NANO_2014_5_6_a9,
     author = {Jun Li and Zhen Hu and Yuanjun Song and Yudong Huang and V. V. Zuev},
     title = {New route to poly (2,6-diimidaazo(4,5-b: 4',5'-e) pyridinelene-1,4(2,5-dihydroxy)-phenylene) {(PIPD)} and high modulus fiber on it basis},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {829--835},
     year = {2014},
     volume = {5},
     number = {6},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2014_5_6_a9/}
}
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Jun Li; Zhen Hu; Yuanjun Song; Yudong Huang; V. V. Zuev. New route to poly (2,6-diimidaazo(4,5-b: 4',5'-e) pyridinelene-1,4(2,5-dihydroxy)-phenylene) (PIPD) and high modulus fiber on it basis. Nanosistemy: fizika, himiâ, matematika, Tome 5 (2014) no. 6, pp. 829-835. http://geodesic.mathdoc.fr/item/NANO_2014_5_6_a9/