Geodesic
Synthesis and photocatalytic activity of quasi-one-dimensional (1-D) solid solutions Ti$_{1-x}$M$_{x}$O$_{2-2x/2}$ (M(III)= Fe(III), Ce(III), Er(III), Tb(III), Eu(III), Nd(III) and Sm(III), $0\le x\le 0.1$)
Nanosistemy: fizika, himiâ, matematika, Tome 5 (2014) no. 4, pp. 553-563

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Quasi-one-dimensional (1–D) solid solutions Ti$_{1-x}$M$_{x}$O$_{2-2x/2}$ (M(III)= Fe(III), Ce(III), Er(III), Tb(III), Eu(III), Nd(III), Sm(III), $0\le x\le 0.1$) with the anatase structure have been synthesized by heating glycolate Ti$_{1-x}$M$_{x}$(OCH$_2$CH$_2$O)$_{2-x/2}$ in air at a temperature above 450$^\circ$C. A method was proposed for the production ofiron-and carbon-doped titanium dioxide with the anatase structure Ti$_{1-x}$Fe$_{x}$O$_{(2-x/2)-y}$C$_y$ and of composites basedthereon containing an excessive carbon content. It was shown that the oxide solid solutions exhibit photocatalyticactivity in the hydroquinone photooxidation reaction during irradiation in the ultraviolet spectrum. A correlationwas established between the hydroquinone oxidation rate and the concentration of the substituting ions “M” in thecatalyst. In the framework of the theory of ion-covalent binary solid solutions, a correlation was found betweenthe energy of the photocatalytic reaction and the estimated mixing enthalpy of binary solid solutions formation.
Keywords: glycolates, three-charged cations, anatase, synthesis, photocatalytic properties. 
@article{NANO_2014_5_4_a9,
     author = {E. V. Polyakov and V. N. Krasil'nikov and O. I. Gyrdasova and L. Yu. Buldakova and M. Yu. Yanchenko},
     title = {Synthesis and photocatalytic activity of quasi-one-dimensional {(1-D)} solid solutions {Ti}$_{1-x}${M}$_{x}${O}$_{2-2x/2}$ {(M(III)=} {Fe(III),} {Ce(III),} {Er(III),} {Tb(III),} {Eu(III),} {Nd(III)} and {Sm(III),} $0\le x\le 0.1$)},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {553--563},
     publisher = {mathdoc},
     volume = {5},
     number = {4},
     year = {2014},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2014_5_4_a9/}
}
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AU  - M. Yu. Yanchenko
TI  - Synthesis and photocatalytic activity of quasi-one-dimensional (1-D) solid solutions Ti$_{1-x}$M$_{x}$O$_{2-2x/2}$ (M(III)= Fe(III), Ce(III), Er(III), Tb(III), Eu(III), Nd(III) and Sm(III), $0\le x\le 0.1$)
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%T Synthesis and photocatalytic activity of quasi-one-dimensional (1-D) solid solutions Ti$_{1-x}$M$_{x}$O$_{2-2x/2}$ (M(III)= Fe(III), Ce(III), Er(III), Tb(III), Eu(III), Nd(III) and Sm(III), $0\le x\le 0.1$)
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E. V. Polyakov; V. N. Krasil'nikov; O. I. Gyrdasova; L. Yu. Buldakova; M. Yu. Yanchenko. Synthesis and photocatalytic activity of quasi-one-dimensional (1-D) solid solutions Ti$_{1-x}$M$_{x}$O$_{2-2x/2}$ (M(III)= Fe(III), Ce(III), Er(III), Tb(III), Eu(III), Nd(III) and Sm(III), $0\le x\le 0.1$). Nanosistemy: fizika, himiâ, matematika, Tome 5 (2014) no. 4, pp. 553-563. http://geodesic.mathdoc.fr/item/NANO_2014_5_4_a9/