Polythermal solubility and complex thermal analysis of watersoluble trismalonate of light fullerene -- C$_{60}$ [= C(COOH)$_{2}$]$_{3}$
Nanosistemy: fizika, himiâ, matematika, Tome 5 (2014) no. 3, pp. 435-440.

Voir la notice de l'article provenant de la source Math-Net.Ru

The poly-thermal solubility of the tris-malonate C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ – H$_{2}$O binary system was investigated from 20 – 80$^\circ$C with the help of the method of isotherm saturation in ampoules. Concentration of tris-malonate C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ in solutions was determined by light absorption at 330 nm. A diagram of the solubility is non-monotonic, consisting of 2 branches, which correspond to 2 different crystal-hydrates of C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ and one non-variant point, corresponding to the saturation both crystal-hydrates. Complex thermal analysis of C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ crystal hydrates, in equilibrium with a saturated aqueous solution at room temperature, was performed from 20 – 600$^\circ$C. Consecutive effects of the losses of C=O and C=O + H$_{2}$O were determined.
Keywords: tris-malonate of light fullerene, solubility, density, complex thermal analysis.
@article{NANO_2014_5_3_a12,
     author = {K. N. Semenov and N. A. Charykov and A. S. Kritchenkov and I. A. Cherepkova and O. S. Manyakina and D. P. Tyurin and A. A. Shestopalova and V. A. Keskinov and K. V. Ivanova and N. M. Ivanova and D. G. Letenko and V. A. Nikitin and E. L. Fokina and I. A. Pestov and A. O. Netrusov},
     title = {Polythermal solubility and complex thermal analysis of watersoluble trismalonate of light fullerene -- {C}$_{60}$ [= {C(COOH)}$_{2}$]$_{3}$},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {435--440},
     publisher = {mathdoc},
     volume = {5},
     number = {3},
     year = {2014},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/NANO_2014_5_3_a12/}
}
TY  - JOUR
AU  - K. N. Semenov
AU  - N. A. Charykov
AU  - A. S. Kritchenkov
AU  - I. A. Cherepkova
AU  - O. S. Manyakina
AU  - D. P. Tyurin
AU  - A. A. Shestopalova
AU  - V. A. Keskinov
AU  - K. V. Ivanova
AU  - N. M. Ivanova
AU  - D. G. Letenko
AU  - V. A. Nikitin
AU  - E. L. Fokina
AU  - I. A. Pestov
AU  - A. O. Netrusov
TI  - Polythermal solubility and complex thermal analysis of watersoluble trismalonate of light fullerene -- C$_{60}$ [= C(COOH)$_{2}$]$_{3}$
JO  - Nanosistemy: fizika, himiâ, matematika
PY  - 2014
SP  - 435
EP  - 440
VL  - 5
IS  - 3
PB  - mathdoc
UR  - http://geodesic.mathdoc.fr/item/NANO_2014_5_3_a12/
LA  - en
ID  - NANO_2014_5_3_a12
ER  - 
%0 Journal Article
%A K. N. Semenov
%A N. A. Charykov
%A A. S. Kritchenkov
%A I. A. Cherepkova
%A O. S. Manyakina
%A D. P. Tyurin
%A A. A. Shestopalova
%A V. A. Keskinov
%A K. V. Ivanova
%A N. M. Ivanova
%A D. G. Letenko
%A V. A. Nikitin
%A E. L. Fokina
%A I. A. Pestov
%A A. O. Netrusov
%T Polythermal solubility and complex thermal analysis of watersoluble trismalonate of light fullerene -- C$_{60}$ [= C(COOH)$_{2}$]$_{3}$
%J Nanosistemy: fizika, himiâ, matematika
%D 2014
%P 435-440
%V 5
%N 3
%I mathdoc
%U http://geodesic.mathdoc.fr/item/NANO_2014_5_3_a12/
%G en
%F NANO_2014_5_3_a12
K. N. Semenov; N. A. Charykov; A. S. Kritchenkov; I. A. Cherepkova; O. S. Manyakina; D. P. Tyurin; A. A. Shestopalova; V. A. Keskinov; K. V. Ivanova; N. M. Ivanova; D. G. Letenko; V. A. Nikitin; E. L. Fokina; I. A. Pestov; A. O. Netrusov. Polythermal solubility and complex thermal analysis of watersoluble trismalonate of light fullerene -- C$_{60}$ [= C(COOH)$_{2}$]$_{3}$. Nanosistemy: fizika, himiâ, matematika, Tome 5 (2014) no. 3, pp. 435-440. http://geodesic.mathdoc.fr/item/NANO_2014_5_3_a12/