Са$_{3}$(РО$_{4}$)$_{2}$ polymorphism

P. V. Evdokimov; V. I. Putlayev; D. A. Merzlov; T. B. Shatalova; Т. V. Safronova; E. C. Klimashina; B. R. Churagulov

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Са$_{3}$(РО$_{4}$)$_{2}$ polymorphism

P. V. Evdokimov ; V. I. Putlayev ; D. A. Merzlov ; T. B. Shatalova ; Т. V. Safronova ; E. C. Klimashina ; B. R. Churagulov

Nanosistemy: fizika, himiâ, matematika, Tome 4 (2013) no. 1, pp. 48-53.

Voir la notice de l'article provenant de la source Math-Net.Ru

Résumé

The present article is devoted to the $\beta\to\alpha$ phase transformation of Са$_{3}$(РО$_{4})$. This phase transformation is low-rate, first-order reconstructive transition, $\alpha$-Са$_{3}$(РО$_{4}$)$_{2}$ can be obtained in the course of low-rate cooling (ca. 5$^\circ$С/min). Transformation $\alpha\to\alpha$' is a high-rate, first-order deformation phase transition; such a fact indicates that $\alpha$'-Са$_{3}$(РО$_{4}$)$_{2}$ cannot be obtained even by quenching.

Keywords: tricalcium phosphate, deformation phase transition, first-order transition.
Mots-clés : polymorphism, reconstructive phase transition

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     author = {P. V. Evdokimov and V. I. Putlayev and D. A. Merzlov and T. B. Shatalova and {\CYRT}. V. Safronova and E. C. Klimashina and B. R. Churagulov},
     title = {{\CYRS}{\cyra}$_{3}${({\CYRR}{\CYRO}}$_{4}$)$_{2}$ polymorphism},
     journal = {Nanosistemy: fizika, himi\^a, matematika},
     pages = {48--53},
     publisher = {mathdoc},
     volume = {4},
     number = {1},
     year = {2013},
     language = {ru},
     url = {http://geodesic.mathdoc.fr/item/NANO_2013_4_1_a3/}
}

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P. V. Evdokimov; V. I. Putlayev; D. A. Merzlov; T. B. Shatalova; Т. V. Safronova; E. C. Klimashina; B. R. Churagulov. Са$_{3}$(РО$_{4}$)$_{2}$ polymorphism. Nanosistemy: fizika, himiâ, matematika, Tome 4 (2013) no. 1, pp. 48-53. http://geodesic.mathdoc.fr/item/NANO_2013_4_1_a3/