Noncoincidence of the Markov and Lagrange spectra
Matematičeskie zametki, Tome 3 (1968) no. 2, pp. 195-200.

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Using continued fractions, the paper constructs an example of a real number contained in the Markov spectrum, but not in the Lagrange spectrum.
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     author = {G. A. Freiman},
     title = {Noncoincidence of the {Markov} and {Lagrange} spectra},
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G. A. Freiman. Noncoincidence of the Markov and Lagrange spectra. Matematičeskie zametki, Tome 3 (1968) no. 2, pp. 195-200. http://geodesic.mathdoc.fr/item/MZM_1968_3_2_a9/