Geodesic
Solid-state synthesis of Cu$_6$Sn$_5$ intermetallic in Sn/Cu thin films
Žurnal Sibirskogo federalʹnogo universiteta. Matematika i fizika, Tome 15 (2022) no. 4, pp. 493-499

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The study results of solid-state synthesis of the Cu$_6$Sn$_5$ intermetallic in the Sn/Cu thin-film systems during vacuum annealing from room temperature to $300^\circ$C are presented. The initiation and finishing temperatures of the solid-state reaction between the Cu and Sn nanolayers and the phase composition of the reaction products were determined. The synthesized thin films were monophasic and consisted of the hexagonal $\eta$-Cu$_6$Sn$_5$ phase. It is assumed that the initiation temperature of the solid-state reaction in Sn/Cu thin films is associated with the start temperature of the reverse polymorphic transformation $\eta' \rightarrow \eta$ between the monoclinic and hexagonal Cu$_6$Sn$_5$ phases.
Keywords: thin films, solid-state synthesis, $\eta \leftrightarrow \eta'$ reversible polymorphic transformations.
Mots-clés : Cu$_6$Sn$_5$ intermetallic 
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     author = {Liudmila E. Bykova and Victor G. Myagkov and Yuri Yu. Balashov and Victor S. Zhigalov and Gennady S. Patrin},
     title = {Solid-state synthesis of {Cu}$_6${Sn}$_5$ intermetallic in {Sn/Cu} thin films},
     journal = {\v{Z}urnal Sibirskogo federalʹnogo universiteta. Matematika i fizika},
     pages = {493--499},
     publisher = {mathdoc},
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     number = {4},
     year = {2022},
     language = {en},
     url = {http://geodesic.mathdoc.fr/item/JSFU_2022_15_4_a7/}
}
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Liudmila E. Bykova; Victor G. Myagkov; Yuri Yu. Balashov; Victor S. Zhigalov; Gennady S. Patrin. Solid-state synthesis of Cu$_6$Sn$_5$ intermetallic in Sn/Cu thin films. Žurnal Sibirskogo federalʹnogo universiteta. Matematika i fizika, Tome 15 (2022) no. 4, pp. 493-499. http://geodesic.mathdoc.fr/item/JSFU_2022_15_4_a7/