Geodesic
Solid-state synthesis of Cu$_6$Sn$_5$ intermetallic in Sn/Cu thin films
Žurnal Sibirskogo federalʹnogo universiteta. Matematika i fizika, Tome 15 (2022) no. 4, pp. 493-499.

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The study results of solid-state synthesis of the Cu$_6$Sn$_5$ intermetallic in the Sn/Cu thin-film systems during vacuum annealing from room temperature to $300^\circ$C are presented. The initiation and finishing temperatures of the solid-state reaction between the Cu and Sn nanolayers and the phase composition of the reaction products were determined. The synthesized thin films were monophasic and consisted of the hexagonal $\eta$-Cu$_6$Sn$_5$ phase. It is assumed that the initiation temperature of the solid-state reaction in Sn/Cu thin films is associated with the start temperature of the reverse polymorphic transformation $\eta' \rightarrow \eta$ between the monoclinic and hexagonal Cu$_6$Sn$_5$ phases.
Keywords: thin films, solid-state synthesis, $\eta \leftrightarrow \eta'$ reversible polymorphic transformations.
Mots-clés : Cu$_6$Sn$_5$ intermetallic 
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Liudmila E. Bykova; Victor G. Myagkov; Yuri Yu. Balashov; Victor S. Zhigalov; Gennady S. Patrin. Solid-state synthesis of Cu$_6$Sn$_5$ intermetallic in Sn/Cu thin films. Žurnal Sibirskogo federalʹnogo universiteta. Matematika i fizika, Tome 15 (2022) no. 4, pp. 493-499. http://geodesic.mathdoc.fr/item/JSFU_2022_15_4_a7/

[1] F. Somidina, H. Maenob, M.A.A. Mohd Sallehc, X.Q. Trana, S.D. McDonald, S. Matsumurab, K. Nogita, “Characterising the polymorphic phase transformation at a localised point on a Cu$_6$Sn$_5$ grain”, Materials Characterization, 138 (2018), 113–119 | DOI

[2] Q. Yin, F. Gao, Z. Gu, J. Wang, E.A. Stach, G. Zhou, “Interface dynamics in one-dimensional nanoscale Cu/Sn couples”, Acta Mater., 125 (2017), 136–144 | DOI

[3] M.A.A. Mohd Salleh, S.D. McDonald, H. Yasuda, A. Sugiyama, K. Nogita, “Rapid Cu$_6$Sn$_5$ growth at liquid Sn/solid Cu interfaces”, Scr. Mater., 100 (2015), 17–20 | DOI

[4] M.A.A.M. Salleh, C.M. Gourlay, J.W. Xian, S.A. Belyakov, H. Yasuda, S.D. McDonald, K. Nogita, “In situ imaging of microstructure formation in electronic interconnections”, Sci. Rep., 7 (2017), 40010, 11 pp. | DOI

[5] J.M. Poate, K.N. Tu, J. W. Mayer (eds), Thin Films-Interdiffusion and Reaction, Willey-Interscience, New York, 1978

[6] R. Pretorius, C.C. Theron, A. Vantomme, J.W. Mayer, “Compound Phase Formation in Thin Film Structures”, Crit. Rev. Solid State Mater., Sci., 24 (1999), 1–62

[7] J. J. Hoyt, L.N. Brush, “On the nucleation of an intermediate phase at an interface in the presence of a concentration gradient”, J. Appl. Phys., 78 (1995), 1589–1594

[8] C.M. Comrie, D. Smeets, K.J. Pondo, C. van der Walt, J. Demeulemeester, W. Knaepen, C. Detavernier, A. Habanyama, A. Vantomme, “Determination of the dominant diffusing species during nickel and palladium germanide formation”, Thin Solid Films, 526 (2012), 261–268 | DOI

[9] K.S. Chi, L.J. Chen, “Dominant diffusing species in the growth of amorphous interlayer between Yb metal thin films and crystalline Si”, J. Appl. Phys., 92 (2002), 927–931 | DOI

[10] V.G Myagkov, L.E. Bykova, V.S. Zhigalov, A.A. Matsynin, D.A. Velikanov, G.N. Bondarenko, “Solid-state synthesis, rotatable magnetic anisotropy and characterization of Co$_{1-x}$Pt$_x$ phases in 50Pt/50fccCo(001) and 32Pt/68fccCo(001) thin films”, J. Alloys Compd., 861 (2021), 157938, 9 pp. | DOI

[11] N. Saunders, A.P. Miodownik, “The Cu-Sn (Copper-Tin) system”, Bull. Alloy Phase Diagr., 11 (1990), 278–287

[12] V.G. Myagkov, L.E. Bykova, S.M. Zharkov, G.N. Bondarenko, “Formation of NiAl Shape Memory Alloy Thin Films by a Solid-State Reaction”, Solid State Phenomena, 138 (2008), 377–384 | DOI

[13] V.G. Myagkov, L.E. Bykova, L.A. Li, I.A. Turpanov, G.N. Bondarenko, “Solid-phase reactions, self-propagating high-temperature synthesis, and martensitic transformations in thin films”, Dokl. Phys., 47 (2002), 95–98 | DOI

[14] V.S. Zhigalov, V.G. Myagkov, O.A. Bayukov, L.E. Bykova, G.N. Bondarenko, A.A. Matsynin, “Phase transformations in Mn/Fe(001) films: Structural and magnetic investigations”, JETP Lett., 89 (2009), 621–625 | DOI

[15] V.G. Myagkov, L.E. Bykova, G.N. Bondarenko, “Solid-state synthesis and martensitic transformations in thin films”, Dokl. Phys., 48:1 (2003), 30–33 | DOI

[16] V.G. Myagkov, Yu.L. Mikhlin, L.E. Bykova, G.V. Bondarenko, G.N. Bondarenko, “Long-range nature of chemical interaction in solid-phase reactions: Formation of martensite phases of an Au-Cd Alloy in Cd/Fe/Au film systems”, Dokl. Phys. Chem., 431 (2010), 52–56 | DOI

[17] H. Zhang, C.W. Wei, J.J. Han, H.J. Cao, H.T. Chen, M.Y. Li, “Growth evolution and formation mechanism of $\eta'$-Cu$_6$Sn$_5$ whiskers on $\eta$-Cu$_6$Sn$_5$ intermetallics during room-temperature ageing”, Acta Mater., 183 (2020), 340–349 | DOI

[18] A. Baldi, T.C. Narayan, A.L. Koh, J.A. Dionne, “In situ detection of hydrogen-induced phase transitions in individual palladium nanocrystals”, Nat. Mater., 13 (2014), 1143–1148 | DOI

[19] F. Gao, Z. Gu, “Melting Temperature of Metallic Nanoparticles”, Handbook of Nanoparticles, eds. Aliofkhazraei M., Springer, Cham, 2016, 661–690 | DOI

[20] K.N. Tu, “Interdiffusion and reaction in bimetallic Cu-Sn thin films”, Acta metall., 21 (1973), 347–354